锌、镉配位聚合物的合成、晶体结构及荧光性质（英文）

Synthesis, Crystal Structure and Fluorescent Properties of Zinc,Cadmium Coordination Polymers

通过水热法合成了2个金属-有机配位聚合物[Zn(boba)(bix)]n(1)和[Cd(L1)(L2)]2n·nH2O(2)(H2boba=4,4′-(丁烷-1,2-二氧基)-二苯甲酸,bix=1,4-双(咪唑基-1-基)苯,H2L1=4-(羧基甲氧基)苯甲酸,L2=2-(4-羟基)-1H-咪唑并[4,5-f][1,10]菲咯啉)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。配合物1为二维网状结构,配合物2为一维双链结构。此外,还研究了它们的荧光性质。

Two metal-organic coordination polymers [Zn（boba）（bix）]n（1） and [Cd（L1）（L2）]2n·nH2O（2）（H2boba=4,4′-（butane-1,4-diyldioxy）dibenzoic acid, bix=1,4-bis（imidazol-1-yl）-benzene, H2L1=4-（carboxy-methoxy）-benzoic acid,L2=2-（4-hydroxyl）-1H-imidazo[4,5-f][1,10]phenanthroline） have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. Complex 1 is 2D network structure, complex 2 exhibits 1D double chain structure. Moreover, their luminescent properties have been investigated in the solid state. CCDC： 987090, 1; 988451, 2.