摘要
石油套管用钢(/%:0.26~0.29C,0.25~0.35Si,0.40~0.50Mn,≤0.009P,≤0.004S,0.95~1.05Cr,0.09~0.11V,0.02~0.04Al,0.015~0.020Ti,≤0.006 0N)的生产流程为铁水预处理-120 t BOF-吹氩-LF-喂CaSi线-RH-合金化-喂CaSi线-软吹氩-Φ220 mm圆坯连铸工艺。通过热力学分析得出钢中N含量超过50×10^(-6)以及工业试验得出生产的圆铸坯中的N含量为67×10^(-6)时,在铸坯中易形成2μm以上的TiN夹杂。通过控制BOF终点[N]≤30×10^(-6),LF终点[S]≤25×10^(-6),[O]≤25×10^(-6),[N]≤35×10^(-6),RH合金化后终点[N]≤35×10^(-6),[H]≤1.5×10^(-6),稳定喂CaSi线速度300~400 m/min,控制中间包[N]≤40×10^(-6),严格连铸保护浇铸工艺,则铸坯中的N含量≤50×10^(-6),钢中TiN夹杂数量显著下降,未发现大尺寸TiN夹杂物。
The production flow sheet for oil casing tube steel (/% : 0. 26 -0. 29C, 0. 25 - 0. 35Si, 0. 40 -0. 50Mn, ≤0. 009P, ≤0. 004S, 0. 95 - 1.05Cr, 0. 09 -0. llV, O. 02 -0. 04A1, 0. 015 -0. 020Ti, ≤0. 006 ON) is hot metal pretreat- ment-120 t BOF-argon blowing-LF-CaSi wire feeding-RH-Alloying-CaSi wire feeding-soft argon blowing-Ф200 mm round bloom casting process. By commercial test as the N content in produced round casting bloom is 67 x 10^-6 and by thermodynamic analysis as the N content in steel is more than 50 × 10^-6, the more than 2 μm TiN inclusions easily form in casting bloom. With controlling BOF end [ N] ~〈30 x 10^-6, LF end [ S] ≤25 × 10^-6, [ O] ~〈25 x 10^-6 and [ N] ≤35 x 10^-6, after alloying RH end [N] ~〈35 x 10^-6 and [H]≤1.5 × 10^-6, stably feeding CaSi wire speed 300 -400 m/min and controlling tundish [N] 10^-640 × 10^-6 and strict casting-shielding process, the N content in casting bloom shall be ≤50 × 10^-6 , the a- mount of TiN inclusions in steel decreases markedly and there are not larger size TiN inclusions to be found in steel.
出处
《特殊钢》
北大核心
2014年第5期30-33,共4页
Special Steel
基金
国家自然科学基金资助项目(51274032)