N_2O的近红外腔增强吸收光谱技术研究

Near Infrared Cavity Enhanced Absorption Spectroscopy Study of N_2O

以外腔式可调谐、窄线宽近红外半导体激光为光源,以一对曲率半径r=1 000mm的宽带高反射率平凹镜(反射率R=99.97%)构成的腔长为650mm的对称高精度光学稳定腔,建立了腔增强吸收光谱系统。详细研究了纯净N2O气体、以及N2O和N2的混合气体在不同浓度和不同气压下、中心波长位于6 561.39cm-1的腔增强吸收光谱、光谱强度和谱线宽度,该腔增强吸收光谱系统的有效吸收光程可达1 460km。获得了光谱线宽与气体压强的关系曲线,导出了波数6 561.39cm-1处N2对N2O的压力展宽系数为(0.114±0.004)cm-1·atm-1。采用该腔增强吸收光谱系统,开展了N2O气体检测研究,建立可用于定量检测的N2O气体腔增强吸收光谱强度与气体浓度关系曲线,获得了2.34×10-7cm-1的检测灵敏度,多次重复测量的相对标准偏差(RSD)为1.73%,在微量N2O气体检测中具有很好的应用前景。

Using a tunable near infrared external cavity diode laser and a 650mm long high finesse optical cavity consisting of two highly reflective （R= 99. 97% at 6 561. 39 cm-1 ）plan-concave mirrors of curvature radius ~1 000 mm,a cavity enhanced ab-sorption spectroscopy （CEAS）system was made.The absorption spectra centered at 6 561. 39 cm-1 of pure N2 O gas and gas mixtures of N2 O and N2 were recorded.According to the absorption of N2 O at 6 561. 39 cm-1 in the cavity,the measured effec-tive absorption path was about 1 460 km.The spectra line intensity and line-width of N2 O centered at 6 561. 39 cm-1 were care-fully studied.The relationship between the line-width of absorption spectra and the gas pressure was derived.The pressure broadening parameter of N2 gas for N2O line centered at 6 561. 39 cm-1 was deduced and given a value of ^（0. 114＆#177;0. 004）＆amp;nbsp;cm-1 ＆#183;atm-1 .The possibility to detect trace N2 O gas in mixture using this CEAS system was investigated.By recording the ab-sorption spectra of N2 O gas mixtures at different concentration,the relationship between the line intensity and gas concentration was derived.The minimum detectable absorption was found to be 2. 34＆#215;10-7 cm-1 using this cavity enhanced absorption spec-troscopy system.And te measurement precision in terms of relative standard deviation （RSD）for N2 O is ~1. 73%,indicating the possibility of using the cavity enhanced absorption spectroscopy system for micro gas N2 O analysis in the future.