摘要
在合成CPAM乳液的基础上,用DMC对Na-MMT进行插层有机化改性制备O-MMT,采用分散聚合法合成CPAM-MMT乳液絮凝剂,并对其形态和性能表征,得出:PCPAM-MMT杂化絮凝剂在水中的形态显树枝状,MMT有助于提高模拟污水高岭土的絮凝性能,最佳添加量为10 mg·L-1;PCPAM-MMT杂化絮凝剂对Cr6+具有较强的吸附能力,CPAM对Cr(VI)的脱色率是18%.而CPAM-MMT(1)的脱色率是28%.
A CPAM-MMT hybrid polymer was synthesized through dispersing polymerization with Acrylamide ( AM) , the organic modified montmorillonite ( O-MMT) , 2-methylacryloylxyethyl trimethyl ammonium chloride ( DMC) and its flocculation performance was also studied .The experimental results showed that morphology of the CPAM-MMT hybrid polymer was a multi-branched structure which helps to entrap more suspended colloidal-particles and gives a better bridging capacity , the flocculation ability of the CPAM-MMT hybrid polymer on the kaolin suspensions was better than that of CPAM and its optimum dosage was about 10 mg · L-1 , the CPAM-MMT hybrid polymer possessed the adsorption function on Cr ( VI) ions, which made the decolorization rate on Cr(VI) larger than that of the CPAM, the CPAM on Cr(VI)was 18%.However, the CPAM-MMT(1) hybrid polymer was 28%.
出处
《广州大学学报(自然科学版)》
CAS
2014年第3期34-39,共6页
Journal of Guangzhou University:Natural Science Edition
基金
supported by Science and Technology Project of Guangzhou(2013J4100019)
关键词
蒙脱土
插层
杂化聚合物
分散聚合
絮凝剂
montmorillonite
intercalation
hybrid polymer
dispersing polymerization
flocculation