N-胺化试剂MSH、PHA的合成、表征及热性能

Synthesis and Thermal Property of N-Amination Reagents MSH and PHA

以2,4,6-三甲基苯磺酰氯、2,4,6-三硝基氯苯和乙酰羟肟酸乙酯为原料,合成了标题化合物。利用红外光谱、核磁共振(H谱、C谱)、元素分析、质谱等方法确定了标题化合物的结构,初步探讨了反应机理,优化了合成条件。

The target compounds were synthesized using mesitylene sulfonyl chloride, 2,4,6-trinitrophenyl chloride and ethyl acetohydroxamate as start materials. The structures of compounds were confirmed by IR, 1HNMR, 13 CNMR, elemental analysis and MS. The reaction mechanism was discussed. The synthetic conditions for target compounds were optimized.