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Lipozyme TL IM催化制备零反式脂肪酸人造奶油基料油的研究 被引量:6

Preparation of trans-free fatty acid margarine base oil catalyzed by Lipozyme TL IM
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摘要 以棕榈硬脂和大豆油为原料,通过Lipozyme TL IM催化酯交换法制备零反式脂肪酸人造奶油基料油。对酯交换产物的甘三酯组成、固体脂肪含量、结晶速度等进行了分析,结果发现酯交换产物甘三酯组成发生了较大变化,固体脂肪含量降低,结晶速度明显提高,X-射线衍射分析表明酯交换产物为β'晶型,差示扫描量热分析表明酯交换产物具有较宽的塑性范围,适合用于制备人造奶油。 The trans - free fatty acid margarine base oil was prepared by the transesterification of palm stearin and soybean oil with Lipozyme TL IM as catalyst, and the triacylglyceride composition,solid fat content and crystallization rate of the transesterification product were analyzed. The results indicated that the triacylglyceride composition of the transesterification product changed significantly, the solid fat con-tent decreased and the crystallization rate increased markedly. The transesterification product contained most β’ crystal by X - ray diffraction analysis and had a wide plastic range by differential scanning calo-rimetry analysis,which was suitable for preparing margarine.
出处 《中国油脂》 CAS CSCD 北大核心 2014年第8期42-46,共5页 China Oils and Fats
基金 大连理工大学基本科研业务费专项项目(DUT12JN09)
关键词 酶催化 零反式脂肪酸 人造奶油 LIPOZYME TL IM 棕榈硬脂 enzyme - catalysis trans - free fatty acid margarine Lipozyme TL IM palm stearin
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参考文献11

  • 1ZEITOUN M A M, NEFF W E, LIST G R, et al. Physical properties of interesterified fat blends [ J]. J Am Oil Chem Soc, 1993,70(5) : 467 -471.
  • 2ZHANG H, XU X B, NILSSON J, et al. Production of mar- garine fats by enzymatic interesterificatiort with silica - granulated Thermomyces lanuginosa lipase in a large - scale study [J]. J Am Oil Chem Soc, 2001,78(1) : 57 -64.
  • 3COSTALES - RODRIGUEZ R, GIBON V, VERHER, et al. Chemical and enzymatic interesterification of a blend of palm stearin: soybean oil for low trans - margarine formula- tion [J]. J Am Oil Chem Soc, 2009,86 (7) : 681 -697.
  • 4杨博,杨继国,李行方,林炜铁.棕榈油硬脂和大豆油酶法酯交换的研究[J].中国油脂,2006,31(1):27-29. 被引量:9
  • 5苏国忠,牟英,杨天奎.新型中长链甘三酯的制备及其在人造奶油中的应用[J].中国油脂,2012,37(11):49-53. 被引量:5
  • 6RADIZIAN R, SUE T T, OOI C K, et al. Pocket book of palm oil uses [ M ]. Malaysain: Malaysain of Palm Oil Board(MPOB) ,2009:39 -43.
  • 7WIEDERMANN L H. Margarine and margarine oil, formu- lation and control [ J ]. J Food Sci Technol, 1978,55 : 823 - 828.
  • 8GOLD I L, UKHUN M E, AKOH C C. Characteristics of eutectic compositions of restructured palm oil olein, palm kernel oil and their mixtures [ J ]. J Am Oil Chem Soc, 2011,88(11) : 1659 -1667.
  • 9RAJAH K K. Fats in food technology [M]. Blackwell,2002.
  • 10OSORIO N M, GUSMAO J H, DA FONSECA M M R, et al. Lipase - catalysed interesterification of palm stearin with soybean oil in a continuous fluidised - bed reactor [J]. Eur J Lipid Sci Tech,2005,107(7/8) : 455 -463.

二级参考文献26

  • 1Sridhar R,Lakshminarayana G,Kaimal T.Modification of selected Indian vegetable fats into cocoa butter substitutes by lipase-catalyzed ester interchange[J].J.Am.Oil Chem.Soc.,1991,68:726-730.
  • 2Forsell P,Paravuori P,Linko P,et al.Enzymatic transesterification of rapeseed oil and lauric acid in a continuous resactor[J].J.Am.Oil Chem.Soc.,1993,70:1105-1109.
  • 3Malcata FX,Reyes H,Garcya H,et al.Kinetic and mechanisms of reactions catalyzed by immobilized lipases[ J ].Enzyme Microb.Technol.,1992,14:426-446.
  • 4Foglia T A,Pertruso K,Feairheller S H.Enzymatic interesterification of tallow sunflower oil mixtures[ J ].J.Am.Oil Chem.Soc.,1993,70:281-285.
  • 5Weiss T J,Jacobson G A,Wiedermann L H.Reaction mechanics of sodium methoxide treatment oflard[J].J.Am.Oil Chem.Soc.,1961,38:396-399.
  • 6Wiedermann L H,Weiss T J.Jacobson G A,et al.A comparison of sodium-methoxide treated lards[J].J.Am.Oil Chem.Soc.,1961,38:389-395.
  • 7Bloomer S,Adlercreutz P,Mattiasson B.Triglyceride interesterification by lipases.I.cocoa butter equivalents from fraction palm olein(FPO)[J].J.Am.Oil Chem.Soc.,1990,67:519-524.
  • 8Iwasaki Y,Yamane T.Enzymatic synthesis of structured lipids[J].J.Mol.Catal.B:Enzym.,2000,10:129-140.
  • 9AKOH C C. Food Lipids, Chemistry, Nutrition, and Biotechnology[ M]. 2nd ed. New York, Basel: Marcel Dekker, Inc. ,2002:754 - 760.
  • 10HUIYH.贝雷:油脂化学与工艺学:第3卷[M].徐生庚,裘爱泳,译.5版.北京:中国轻工业出版社,2001:72-121.

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