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异戊二烯与低浓度盐酸的加成反应

Addition Reaction between Isoprene and Low-concentrated Hydrochloric Acid
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摘要 对盐酸浓度由N=5.9 gmol/L到N=10.2 gmol/L、异戊二烯的浓度为10 gmol/L范围的盐酸与异戊二烯加成反应动力学进行了研究,建立了反应速率方程式,基于实验数据回归得到了不同浓度盐酸的各反应速率常数。以四釜连续串联反应器系统为基础,对四釜不同浓度盐酸的反应情况进行了模拟计算,经过调整优化各釜的盐酸浓度和在釜内的停留时间,得到了所需要的反应产物分布。 Under the condition of hydrochloric acid concentration from 5.9 gmol/L to 10.2 gmol/L and isoprene concentration 10 gmol/L the addition reaction dynamics of these two mediums was studied. The equation for reaction rate was established. Through the regression of experiment data, reaction rate factors with different reaction rate were obtained. Based on the reaction system composed of four vessels in serial connection, the simulating calculation for the reactions in these four vessels with different hydrochloric acid concentration was carried out. By adjusting and optimizing the hydrochloric acid concentration and stay duration in each vessels, the distribution of reaction products were obtained.
作者 齐福来
出处 《化工与医药工程》 2014年第4期1-6,共6页 Chemical and Pharmaceutical Engineering
关键词 氯代异戊烯 异戊二烯 氯化氢加成反应 反应动力学 prenyl chloride isoprene hydrochloric acid plus reaction reaction dynamics
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  • 1上海医药设计院.化工工艺设计手册,下册,第1版[M].化学工业出版社,1986..

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