期刊文献+

低温环境下煤表面吸附的均匀性试验 被引量:7

Experimental Study of Coal Surface Adsorption Uniformity in Low Temperature Environment
原文传递
导出
摘要 等量吸附热是表征固体表面吸附非均匀性的重要参数。采用高低温吸附仿真实验装置,对九里山无烟煤、新元贫煤、潘北气肥煤进行瓦斯吸附测试,通过计算等量吸附热与吸附量的关系,探讨从常温(30、20℃)降至低温(-10、-20、-30℃)对煤表面不均匀性的影响。结果表明,不同变质程度煤的瓦斯吸附量都随温度降低而增大;在常温时(30、20℃)煤的等量吸附热随吸附量的增大而减小,表明煤表面能量是不均匀的。降温至-10、-20、-30℃时煤的等量吸附热几乎和吸附量无关,表明煤表面是均匀的。煤吸附瓦斯理论Langmuir方程在低温环境(0℃以下)更加适用。 The isosteric adsorption heat is an important parameter to measure the solid surface inhomogeneity during its adsorption. In this paper a high/low temperature adsorption experiment device is utilized to test the gas adsorption of anthracite coal of Jiulishan coal mine, lean coal of Xinyuan coal mine and gas- fat coal of Panbei coal mine at different temperatures ranging from 30 to- 30℃. Then according to the relationship of isosteric adsorption heat and adsorption capacity, the influence of coal surface inhomogeneity is discussed at ordinary temperatures(30, 20℃)andlowtemperatures(- 10,- 20,- 30℃).Theanalytical resultsshowthat thegasadsorptioncapacities of different coal ranks all increase with the decrease of environmental temperature. In an ordinary temperature environment(30, 20℃)the isosteric adsorption heat of coal decreases as the gas adsorption capacity increases, which indicates that the coal surface energy of adsorption is heterogeneous. But when cooling to- 10,- 20, or- 30℃, theisosteric adsorption heat isalmost irrelevant totheadsorption capacity of coal, which indicates that the coal surface energy of adsorption is uniform. So the Langmuir equation of the coal gas adsorption theory is more suitable to a low temperature environment(below 0℃).
出处 《科技导报》 CAS CSCD 北大核心 2014年第31期71-74,共4页 Science & Technology Review
基金 国家自然科学基金项目(51274090) 河南省瓦斯地质与瓦斯治理重点实验室/省部共建国家重点实验室培育基金项目(WS2012B01) 中国博士后科学基金项目(2013M531673)
关键词 吸附 低温环境 表面均匀性 等量吸附热 adsorption low temperature environment surface uniformity isosteric adsorption heat
  • 相关文献

参考文献15

二级参考文献102

共引文献284

同被引文献43

引证文献7

二级引证文献30

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部