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Improved synthesis of sterically encumbered multibrominated corroles

Improved synthesis of sterically encumbered multibrominated corroles
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摘要 Efficient and easily reproducible synthesis of sterically hindered multibrominated corroles is achieved via dipyrromethane-aldehyde condensation reaction in good yields.Boron trifluoride dietherate(BF_3-Et_2O) is found to be the effective catalyst for cyclization reaction,giving corrole as the major product. Efficient and easily reproducible synthesis of sterically hindered multibrominated corroles is achieved via dipyrromethane-aldehyde condensation reaction in good yields.Boron trifluoride dietherate(BF_3-Et_2O) is found to be the effective catalyst for cyclization reaction,giving corrole as the major product.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2014年第10期1349-1353,共5页 中国化学快报(英文版)
基金 support from National Natural Science Foundation of China(Nos.21171057 and 21371059)
关键词 Brominated corrole Porphyrin Dipyrromethane Boron trifluoride dietherate Brominated corrole Porphyrin Dipyrromethane Boron trifluoride dietherate
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