摘要
Efficient and easily reproducible synthesis of sterically hindered multibrominated corroles is achieved via dipyrromethane-aldehyde condensation reaction in good yields.Boron trifluoride dietherate(BF_3-Et_2O) is found to be the effective catalyst for cyclization reaction,giving corrole as the major product.
Efficient and easily reproducible synthesis of sterically hindered multibrominated corroles is achieved via dipyrromethane-aldehyde condensation reaction in good yields.Boron trifluoride dietherate(BF_3-Et_2O) is found to be the effective catalyst for cyclization reaction,giving corrole as the major product.
基金
support from National Natural Science Foundation of China(Nos.21171057 and 21371059)