摘要
合成了两个新的氮杂环卡宾金属钌配合物1和2,通过核磁共振氢谱、核磁共振碳谱、红外光谱和元素分析对其结构进行了表征,同时,X射线单晶衍射确证了配合物2的结构为cis(I)顺式构型.化合物1和2均能在温和的反应条件下有效催化卤代芳烃和苯硼酸的Suzuki偶联反应,并表现出较高的催化活性.
Two new complexes 1 and 2 were synthesized and characterized by ^1H NMR, ^13C NMR, IR spectra and elemental analysis, and the crystal structure of cis(I) configuration 2 has been also determined by X-ray crystal diffraction. Complexes 1 and 2 have been found to catalyze the Suzuki coupling reaction of aryl halides and phenylboronic acid with high catalytic activity under the mild reaction conditions.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2014年第10期2063-2067,共5页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.51302156)资助项目~~