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Non-monotonic influence of a magnetic field on the electrochemical behavior of Fe_(78)Si_9B_(13) glassy alloy in NaOH and NaCl solutions

Non-monotonic influence of a magnetic field on the electrochemical behavior of Fe_(78)Si_9B_(13) glassy alloy in NaOH and NaCl solutions
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摘要 The corrosion behavior and microstructure of Fe78Si9B13 glassy alloy in NaOH and NaCl solutions under a 0.02-T magnetic field were investigated through electrochemical testing and scanning electron microscopy (SEM). The current-density prepeak (PP) in the anodic polarization curves in low-concentration NaOH solutions (classified as type I) tends to disappear when the NaOH concentration is increased to 0.4 mol/L and the magnetic field is applied. Under the magnetic field, the height of the second current-density peak is increased in low-concentration NaOH solutions (type I) but decreased in high-concentration NaOH solutions (type Ⅱ). The non-monotonic effect of the magnetic field was similarly observed in the case of polarization curves of samples measured in NaCl solutions, Ring-like corroded patterns and round pits are easily formed under the magnetic field in NaOH and NaC1 solutions. These experimental results were discussed in terms of the magnetohydrodynamic (MHD) effect. The corrosion behavior and microstructure of Fe78Si9B13 glassy alloy in NaOH and NaCl solutions under a 0.02-T magnetic field were investigated through electrochemical testing and scanning electron microscopy (SEM). The current-density prepeak (PP) in the anodic polarization curves in low-concentration NaOH solutions (classified as type I) tends to disappear when the NaOH concentration is increased to 0.4 mol/L and the magnetic field is applied. Under the magnetic field, the height of the second current-density peak is increased in low-concentration NaOH solutions (type I) but decreased in high-concentration NaOH solutions (type Ⅱ). The non-monotonic effect of the magnetic field was similarly observed in the case of polarization curves of samples measured in NaCl solutions, Ring-like corroded patterns and round pits are easily formed under the magnetic field in NaOH and NaC1 solutions. These experimental results were discussed in terms of the magnetohydrodynamic (MHD) effect.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第10期1009-1018,共10页 矿物冶金与材料学报(英文版)
基金 financially supported by the National Natural Science Foundation of China(No.51171091) the Excellent Youth Project of Shandong Natural Science Foundation(No.JQ201012) the Major State Basic Research Development Program of China(No.2012CB825702)
关键词 amorphous alloys electrochemical behavior magnetic field anodic polarization MICROGRAPHS amorphous alloys electrochemical behavior magnetic field anodic polarization micrographs
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