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己二酸合成中高岭土对催化活性组分的载体作用

Loading performance of kaolin carrier for catalytically active component in synthesis of adipic acid
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摘要 以高岭土为载体、钨粉为催化剂前驱物,过氧钨酸为催化剂活性组分,经催化H2O2-环己酮的反应合成了己二酸.利用反应过程中催化活性组分在高岭土表面的选择性吸附,在反应完成后分离出负载过氧钨酸的高岭土并重复循环使用,考察了反应条件对己二酸收率的影响,并测定了过氧钨酸-高岭土的重复使用性能.采用红外光谱分析了高岭土及循环使用的过氧钨酸-高岭土的化学结构.结果表明,载体高岭土能够在反应过程中有效负载过氧钨酸,并且过氧钨酸-高岭土第4次循环利用后其产物的收率基本不随重复利用次数增加而发生变化. Adipic acid was synthesized via the reaction between H2O2 and cyclohexanone reactants in the presence of kaolin as the carrier, tungsten powder as the precursor of the catalyst, and peroxotungstic acid as the catalyst active component. Based on the selective adsorption of the catalyst active component on the surface of kaolin, kaolin-supported peroxotungstic acid was separated and reused in follow-up reactions. The effect of reaction condition on the yield of adipic acid was investigated, the recycling performance of the kaolin-supported peroxotungstic acid was evaluated, and the chemical structure of kaolin and reused kaolin-supported peroxotungstic acid was analyzed by infrared spectrometry. Results indicate that kaolin is able to well support peroxotungstic acid during the reaction. After kaolin-supported peroxotungstic acid is reused for four cycles, the yield of the target product remains nearly unchanged with further increase of the recycling number of kaolin-supported peroxotungstic acid.
出处 《化学研究》 CAS 2014年第6期636-640,共5页 Chemical Research
基金 河南省科技厅科技发展计划项目(112102210008)
关键词 高岭土 载体 催化活性组分 己二酸 合成 kaolin carrier catalytically active component adipic acid synthesis
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参考文献15

  • 1REN S Y,XIE Z F,CAO L Q,et al.Clean synthesis of adipic acid catalyzed by complexes derived from heteropoly acid and glycine[J].Catal Commun,2009,10(5):464-467.
  • 2LI Z,LIN B Z,ZHANG J F,et al.Synthesis,structure and characterization of a inorganic-organic hybrid Dawson polyoxotungstate(H2en)3[P2W18O62]·6.48H2O[J].J Mol Struct,2006,783(1/3):176-183.
  • 3张卫红,王军,任晓乾.Keggin型杂多酸催化合成1-乙酰胺基苯甲基-2-萘酚[J].石油化工,2009,38(3):299-303. 被引量:7
  • 4JIN P,ZHAO Z H,DAI Z P,et al.Inuence of reaction conditions on product distribution in the green oxidation of cyclohexene to adipic acid with hydrogen peroxide[J].Catal Today,2011,175(1):619-624.
  • 5ISARIEBEL Q P,GEOFFROY L,PATRICK C,et al.Clean synthesis of adipic acid from cyclohexene in microemulsions with stearyl dimethyl benzyl ammonium chloride as surfactant:From the laboratory to bench scale[J].Chem Eng J,2012,200/202:357-364.
  • 6BLACH P,BSTROM Z,FRANCESCHI-MESSANT S,et al.Recyclable process for sustainable adipic acid productionin microemulsions[J].Tetrahedron,2010,66(35):7124-7128.
  • 7CAVANI F,FERRONI L,FRATTINI A,et al.Evidence for the presence of alternative mechanisms in the oxidation of cyclohexanone to adipic acid with oxygen,catalysed by Keggin polyoxometalates[J].Appl Catal A,2011,391(1/2):118-124.
  • 8ZHU W S,LI H M,HE X Y,et al.Synthesis of adipic acid catalyzed by surfactant-type peroxotungstates and peroxomolybdates[J].Catal Commun,2008,9(4):551-555.
  • 9LV H Y,REN W Z,LIU P F,et al.One-step aerobic oxidation of cyclohexane to adipic acid using an Anderson-type catalyst[(C18H37)2N(CH3)2]6Mo7O24[J].Appl Catal A,2012,441/442:136-141.
  • 10LI Y,ZHANG X D,SUN L,et al.Fatty acid methyl ester synthesis catalyzed by solid superacid catalyst SO42-/ZrO2-TiO2/La3+[J].Appl Energy,2010,87(1):156-159.

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