以硝基苯基为配体的有机铋化合物的研究进展

Research Progress of Organobismuth Compounds Bearing Nitrophenyl Ligand

由于铋类化合物具有低毒性和低放射性等诸多优良特性,在催化剂、生物医药、功能性材料等多方面的应用研究发展迅速。本文主要介绍了以硝基苯基为配体的有机铋化合物的三种合成方法并进行了比较。着重叙述了采用金属-卤素交换反应的格氏试剂法,该方法具有合成路线简单,实用性强等优点。另外,合成产物的在固化催化方面有良好的应用前景。

Application of many organobimuth compounds in catalysis,biological medicine and functional materials were rapid developed since these compounds of low toxicity and low radioactive characteristics. Three kinds of synthetic methods for organobismuth compounds bearing nitrophenyl ligand and comparison of these synthetic routes were introduced. The use of metal-halogen reaction of Grignard reagent method was emphatically described,which had a simple and practical advantages synthetic route. Furthermore,the synthetic products had good application propects in curing catalysis.