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Species separation of binary colloidal mixtures in the multi-Gauss potential: Effect of depletion

Species separation of binary colloidal mixtures in the multi-Gauss potential: Effect of depletion
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摘要 For the asymmetrical colloidal mixture subject to a confining potential and an external multi-Gauss potential, the separation of species is studied based on the classical density functional theory of simple fluids. The multi-Gauss potential consists of several Gauss barriers, which are distributed along the axial direction with uniform distance. The barrier width,barrier distance, and barrier height are individually adjusted to investigate their effects on the species separation. From the numerical results, it is concluded that in each condition, the competition between the external potential and the depletion potential determines the phase equilibrium and the separation. Species separation appears only in the region where the depletion is dominant. On the contrary, both species are absent in the regions where the external potential takes the absolute advantage. For the asymmetrical colloidal mixture subject to a confining potential and an external multi-Gauss potential, the separation of species is studied based on the classical density functional theory of simple fluids. The multi-Gauss potential consists of several Gauss barriers, which are distributed along the axial direction with uniform distance. The barrier width,barrier distance, and barrier height are individually adjusted to investigate their effects on the species separation. From the numerical results, it is concluded that in each condition, the competition between the external potential and the depletion potential determines the phase equilibrium and the separation. Species separation appears only in the region where the depletion is dominant. On the contrary, both species are absent in the regions where the external potential takes the absolute advantage.
出处 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第12期367-375,共9页 中国物理B(英文版)
基金 Project supported by the Fundamental Research Funds for the Central Universities,China(Grant No.13MS105)
关键词 depletion DEMIXING colloidal mixture density functional theory depletion demixing colloidal mixture density functional theory
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