摘要
We report the photoluminescence(PL) of Eu^3+-doped glass with Bi^3+as a sensitizer. The specific glass system with the strong enhancement of the red emission of Eu3+is obtained by adding a small number of Bi3+ions instead of increasing the Eu^3+ concentration. The emission band of Bi3+overlaps with the excitation band of Eu^3+ and the lifetime decay curves,resulting in a very efficient energy transfer from Bi^3+ to Eu^3+. The probability of energy transfer is strongly dependent on Bi^3+ concentration. In addition, the intensity of 4f–4f transition is much stronger than that of a charge-transfer(CT) band in the excitation spectrum, which indicates that the Na2O–Ca O–Ge O2-Si O2 glass is a suitable red-emitting phosphor with high stability as a candidate for light-emitting diodes(LEDs).
We report the photoluminescence(PL) of Eu^3+-doped glass with Bi^3+as a sensitizer. The specific glass system with the strong enhancement of the red emission of Eu3+is obtained by adding a small number of Bi3+ions instead of increasing the Eu^3+ concentration. The emission band of Bi3+overlaps with the excitation band of Eu^3+ and the lifetime decay curves,resulting in a very efficient energy transfer from Bi^3+ to Eu^3+. The probability of energy transfer is strongly dependent on Bi^3+ concentration. In addition, the intensity of 4f–4f transition is much stronger than that of a charge-transfer(CT) band in the excitation spectrum, which indicates that the Na2O–Ca O–Ge O2-Si O2 glass is a suitable red-emitting phosphor with high stability as a candidate for light-emitting diodes(LEDs).
基金
Project supported by the National Natural Science Foundation of China(Grant Nos.11204113 and 61308091)
the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20115314120001)