摘要
铁催化剂应用于催化硅氢加成反应,具有原料丰富度高、低成本、低毒性等优点,在近几年得到迅速发展.总结了铁催化剂在碳-碳双键、碳-氧双键及其他杂原子不饱和双键硅氢加成反应中的应用,并展望了铁催化剂在有机硅化学领域的应用前景.
Iron catalysts gained great development in hydrosilylation of various types of unsaturated double bond compounds due to their advantages of high raw material abundance, low cost, low toxicity, etc. The applications of iron catalysts are summarized in the hydrosilylation of carbon-carbon double bond, carbon-oxygen double bond and other heteroatomic double bond. The application prospect of iron catalysts in the field of organic silicon chemistry is looked forward.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2014年第11期2195-2201,共7页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.21303035)
浙江省自然科学基金(No.LY14B030007)资助项目~~
关键词
铁配合物
硅氢加成
碳-碳双键
杂原子双键
进展
iron complex
hydrosilylation
carbon-carbon double bond
heteroatomic double bond
progress