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三元材料表面残留锂对电池性能的影响 被引量:6

The Influence of Residual Lithium in Li Ni_xCo_yMn_((1-x-y))O_2 on Battery Safety in This Article
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摘要 安全问题已成为制约锂离子电池向大型化、高能化方向发展的主要障碍。文章概述了从电池自身系统的影响及正极材料对电池的影响两个角度,来分析锂离子电池的安全问题的原因,并对三元正极材料残留锂对电池性能的影响进行分析,提出通过控制残留锂含量来在保障产品电性能的同时控制安全性能。 Safety issues have been the main obstacle to restrict lithium ion batteries to large scale and high energy density. The article summarizes the causes of lithium-ion battery safety issues from two aspects, namely, battery-system and cathode materials. The influence of residual lithium in Li NixCoyMn(1-x-y)O2 on battery safety is analyzed in this article. It is also proposed that not only the electrochemical performance but also the safety performance can be improved by controlling the residual lithium content of Li NixCoyMn(1-x-y)O2.
出处 《广东化工》 CAS 2014年第21期133-134,共2页 Guangdong Chemical Industry
关键词 热稳定性 三元正极材料 锂离子电池 安全 thermal stability LiNixCoyMn(1-x-y)O2 lithium ion battery safety
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参考文献2

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同被引文献46

  • 1张立君,陈慧龙,段恒志,曹雁超,王建军,王瑛.高镍三元正极片放置后残碱质量分数变化研究[J].当代化工,2020,49(10):2226-2229. 被引量:2
  • 2叶乃清,刘长久,沈上越.锂离子电池正极材料LiNiO_2存在的问题与解决办法[J].无机材料学报,2004,19(6):1217-1224. 被引量:39
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  • 6Noh H J, Youn S, Yoon C S, et al. Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2(x=l/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries[J]. Journal of Power Sources, 2013, 233: 121-130.
  • 7Matsumoto K, Kuzuo R, Takeya K deintercalation from LiNi1-x-yCoxAlyO2[J] 81-82(9): 558-561. et al. Effects of CO2 in air on Li Journal of Power Sources, 1999.
  • 8Shizuka K, Kiyohara C, Shima K, et al. Effect of CO2 on layered Lil.zNil-x-yCoxMyO:(M=Al, Mn) cathode materials for lithium ion batteries [J]. Journal of Power Sources, 2007, 166(1): 233-238.
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