摘要
Polychlorinated biphenyls （PCBs） were measured in atmospheric samples collected from the North Pacific to the Arctic Ocean between July and September 2012 to study the atmospheric concentration characteris-tics of PCBs and their gas/particle partitioning. The mean concentration of 26 PCBs （vapor plus particulate phase） （∑PCBs） was 19.116 pg/m^3with a standard deviation of 13.833 pg/m^3. Three most abundant conge-ners were CB-28, -52 and -77, accounting for 43.0% to∑PCBs. The predominance of vapor PCBs （79.0% to∑PCBs） in the atmosphere was observed.∑PCBs were negative correlated with the latitudes and inverse of the absolute temperature （1/T）. The significant correlation for most congeners was also observed between the logarithm of gas/particle partition coefficient （logKp） and 1/T. Shallower slopes （from ∑0.15 to ∑0.46, average ∑0.27） were measured from the regression of the logarithm of sub-cooled liquid vapor pressures （logpoL） and logKP for all samples. The difference of the slopes and intercepts among samples was insignifi-cant （p〉0.1）, implying adsorption and/or absorption processes and the aerosol composition did not differ significantly among different samples. By comparing three models, the J-P adsorption model, the octanol/air partition coefficient （KOA） based model and the soot-air model, the gas/particle partitioning of PCBs in the Arctic atmosphere was simulated more precisely by the soot-air model, and the adsorption onto el-emental carbon is more sensitive than the absorption into organic matters of aerosols, especially for low-chlorinated PCB congeners.
Polychlorinated biphenyls （PCBs） were measured in atmospheric samples collected from the North Pacific to the Arctic Ocean between July and September 2012 to study the atmospheric concentration characteris-tics of PCBs and their gas/particle partitioning. The mean concentration of 26 PCBs （vapor plus particulate phase） （∑PCBs） was 19.116 pg/m^3with a standard deviation of 13.833 pg/m^3. Three most abundant conge-ners were CB-28, -52 and -77, accounting for 43.0% to∑PCBs. The predominance of vapor PCBs （79.0% to∑PCBs） in the atmosphere was observed.∑PCBs were negative correlated with the latitudes and inverse of the absolute temperature （1/T）. The significant correlation for most congeners was also observed between the logarithm of gas/particle partition coefficient （logKp） and 1/T. Shallower slopes （from ∑0.15 to ∑0.46, average ∑0.27） were measured from the regression of the logarithm of sub-cooled liquid vapor pressures （logpoL） and logKP for all samples. The difference of the slopes and intercepts among samples was insignifi-cant （p〉0.1）, implying adsorption and/or absorption processes and the aerosol composition did not differ significantly among different samples. By comparing three models, the J-P adsorption model, the octanol/air partition coefficient （KOA） based model and the soot-air model, the gas/particle partitioning of PCBs in the Arctic atmosphere was simulated more precisely by the soot-air model, and the adsorption onto el-emental carbon is more sensitive than the absorption into organic matters of aerosols, especially for low-chlorinated PCB congeners.
基金
The Chinese Polar Environment Comprehensive Investigation and Assessment Programs under contract Nos 02-01,03-04,04-01 and 04-03
the National Natural Science Fundation of China under contract No.21377032
