期刊文献+

交联壳聚糖树脂负载Fe^(2+)非均相UV/Fenton体系催化氧化降解染料废水的研究

Study on Crosslinked Chitosan Resin Supported Fe^(2+) Heterogeneous UV/Fenton System of Catalytic Oxidation Degradation of Dye Wastewater
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摘要 染料废水是工业废水的的主要来源之一,也是国内外公认的难处理的工业废水。本文探索了交联壳聚糖树脂负载的Fe2+催化剂的制备方法和条件,并以6-硝废水为研究对象,在非均相UV-Fenton体系下对其进行光催化降解。研究表明,在p H为3,催化剂用量0.6g,H2O2用量3.3m L,反应时间为80min,紫外功率为250W,降解率高达97.0%。 Dye wastewater is one of the major sources of industrial wastewater, it is difficult to degradation. This paper explores the methods and conditions of preparation of Fe2+catalyst supported crosslinked chitosan resin, degradated of 6- denitrification of wastewater. The results shows that pH 3, hydrogen peroxide 3.3ml, catalyst 0.6g, UV power 250w, the degradation rate of CODcr could reach to 97.0%.
出处 《科技视界》 2014年第34期55-56,共2页 Science & Technology Vision
基金 重庆市第七届大学生科技创新训练计划项目(201211551015)
关键词 交联壳聚糖树脂 染料废水 催化 UV/Fenton Crosslinked Chitosan Resin UV/Fenton Dye wastewater Catalysis
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参考文献11

  • 1Ai Ni Soon,B.H.Hameed.Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process[J].J.Desalination,269(2011):1-16.
  • 2M.Pera-Titus,V.García-Molina,M.A.Ba·os,J.Giménez,S.Esplugas,Degradation of chlorophe nols by means of advanced oxidation processes:a general review[J].Appl.Catal.,B47(2004):219-256.
  • 3H.Z.Ma,Q.F.Zhuo,B.Wang.Characteristics of Cu O–Mo O3–P2O5catalyst and its catalytic wet oxidation(CWO)of dye wastewater under extremely mild conditions[J].Environ.Sci.Technol.41(2007):7491-7496.
  • 4Carneiro P.A.,Noguire R.F.P.,Zanoni M.V.B.,Homogeneous photo degradation of C.I.Reactive Blue 4 using a photo-Fenton process under artificial and solar irradiation,Dyes Pigment,74(2007):127-132.
  • 5A.Georgi,F.-D.Kopinke,Appl.Catal.B-Environ.58(2005):9-18.
  • 6G.Centi,S.Perathoner,T.Torre,M.G.Verduna,Catalytic wet oxidation with H2O2of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts[J].Catal.Today,55(2000):61-69.
  • 7J.Guo,M.Al-Dahhan.Catalytic wet oxidation of phenol by hydrogen peroxide over pillared clay catalyst[J].Ind.Eng.Chem.Res.,42(2003):2450-2460.
  • 8M.Ying-Shiha,S.Chi-Fanga,L.Jih-Gaw.Degradation of carbofuran in aqueous solution by ultrasound and Fenton processes:effect of system parameters and kinetic study[J].J.Hazard.Mater.,178(2010):320-325.
  • 9J.Fenga,X.Hua,P.L.Yuea,S.Qiaob.Photo Fenton degradation of high concen-tration Orange II(2 m M)using catalysts containing Fe:a comparative study[J].Sep.Purif.Technol,67(2009):213-217.
  • 10禹兴海,韩玉桂,冯雷.交联壳聚糖树脂负载Fe^(2+)非均相UV/Fenton体系催化氧化降解苯酚研究[J].三峡环境与生态,2011,33(3):1-4. 被引量:3

二级参考文献21

  • 1赵晓伟,张然,崔元臣.壳聚糖-Cu(Ⅱ)对H_2O_2的分解催化性能研究[J].河南大学学报(自然科学版),2005,35(3):31-33. 被引量:7
  • 2Tamal Mandal, Sudakshina Maity. Advanced oxidation process and biotreatment: Their roles in combined industrial wastewater treatment[J]. Desalination, 2010, 250(1): 87-94.
  • 3Poyatos J M, Almecija M C. Advanced Oxidation Processes for Wastewater Treatment: State of the Art[J]. Water, Air, Soil Pollution, 2010, 205(1-4):187-204.
  • 4Pamela Chelme-Ayala, Mohamed Gamal El-Din. Degradation of bromoxynil and trifluralin in natural water by direct photolysis and UV plus H2O2 advanced oxidation process[J]. Water Research,2010,44(7) : 2221-2228.
  • 5Aleboyeh A, Kasiri M B. Prediction of azo dye decolorization by UV/H2O2 using artificial neural networks[J]. Dyes and Pigments, 2008, 77(7): 288-294.
  • 6Pichat P. Photocatalytic degradation of aromatic and alicyclic pollutants inwater: by products, pathway and mechanism [J]. Wat. Sci. Technol., 1997,35(4): 73-78.
  • 7Huston P L, Pignatello J J. Reduction of perchloroalkanes by ferrioxalate-generated carboxylate radical preceding mineralization by the photo-Fenton reaction [J]. Environ. Sci. Technol., 1996, 30 (12): 3457-3463.
  • 8Ruppert G, Bauer R. The photo-Fenton reaction-an effective photochemical wastewater treatment process [J]. J. Photochem. Photobiol., A: Chem., 1993,73(1):75-78.
  • 9国家环境保护局<水和废水监测分析方法>编委会.水和废水监测分析方法 [M]. (第3版). 北京:中国环境科学出版社, 1997. 372-374.
  • 10San Y, Pignatello J. Photochemical reactions involved in the total mineralization of 2,4-D by Fe3+/H2O2/UV [J]. Environ. Sci. Technol., 1993,27(2): 304-310.

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