摘要
[目的]以地下水中常见氯代烃污染物三氯乙烯(TCE)为目标污染物,采用自制硫化亚铁(Fe S)作还原剂,探讨两种物质的反应情况。[方法]在厌氧环境下,通过批试验方法研究不同影响因素下硫化亚铁降解TCE的反应动力学并探讨反应机理。[结果]在50℃下,污染物初始浓度为20 mg/L,硫化亚铁浓度为10 g/L,反应48 h后,TCE的去除率可达到80%。硫化亚铁降解TCE的反应符合伪一级动力学反应,反应速率常数(K)为0.032 8 h-1,半衰期为21.13 h。对比试验结果显示,12 h后硫化亚铁吸附TCE达到吸附/解吸平衡,之后TCE的去除以化学降解为主。[结论]硫化亚铁对TCE有一定的降解和吸附作用,反应的主要产物为乙炔。
[Objective] The most widely existent pollutant trichloroethylene (TCE) was chosen as the target pollutant,and the self-made iron sulfide (FeS) was chosen as reductant to investigate the removal ability of chlorinated hydrocarbons.[Method] The batch experiment was used to investigate the reaction kinetics,influencing factors and dechlorination mechanism of TCE in anaerobic environment.[Result] The experimental results show that when the iron sulfide initial concentration is 10 g/L and the initial concentration of pollutant is 20 mg/L,removal efficiency of TCE reaches 80% at 50 ℃ within 48 h.The removal of TCE by iron sulfide follows the pseudo-first order reaction kinetics.Reaction rate constant (K) is 0.032 8 h-1 and half time (t1/2) is 21.13 h.The results of comparison experiment show that the adsorption of TCE on iron sulfide reached adsorption-desorption equilibrium within 12 h,then the removal of TCE primarily by chemical degradation.[Conclusion] Trichloroethylene can be degraded and absorbed by iron sulfide,and the main reaction product is acetylene.
出处
《安徽农业科学》
CAS
2014年第35期12606-12609,共4页
Journal of Anhui Agricultural Sciences
基金
北京市产学研项目(51900265005)
国家科技重大专项(2009ZX07207-008
2009ZX07419-002
2009ZX07207-001)
中央高校基本科研业务费专项(2652013101
2652013086
2652013087)
重点防控重金属汞
铬
铅
镉
砷便携/车载/在线监测仪器开发与应用示范项目(2012YQ060115)