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Geochemical processes and origin of boron isotopes in geothermal water in the Yunnan-Tibet geothermal zone 被引量:11

Geochemical processes and origin of boron isotopes in geothermal water in the Yunnan-Tibet geothermal zone
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摘要 Boron concentrations and isotope compositions have been measured for 93 water samples from the hot springs and drill-holes in the geothermal system in the Yunnan-Tibet Geothermal Belt(YTGB),China.Boron concentrations range from 0.036–472.4ppm,and theδ11B values range from -16.0‰to 13.1‰,indicating the non-marine origin for each geothermal system.We observed a clear binary mixing relationship between the B concentrations and B isotope compositions in Tibet geothermal area.This relationship can be well explained by two sources,i.e.,marine carbonate rocks and magmatic rocks,for the Tibet geothermal water.No evidence supports a mantle contribution to B.In addition,we found that the precipitation only plays a dilution role for B of geothermal waters.δ11B values for the precipitation across the southern Tibetan Plateau area range from -6.0‰ to -6.8‰at least.Due to data scarcity in Yunnan geothermal area,we observed possible different boron sources from the Tibet geothermal system.Comparing it with other geothermal systems in the world,we found that the samples from YTGB have the lowestδ11B values and the largest range of B concentration,which might be related to their special geological background.On the whole,the world geothermalδ11B-Cl/B relation suggests a mixing process between marine and non-marine sources.Additionally,we suggest that B source of B-enriched geothermal waters is mainly from B-enriched crustal country-rocks,instead of mantle. Boron concentrations and isotope compositions have been measured for 93 water samples from the hot springs and drill-holes in the geothermal system in the Yunnan-Tibet Geothermal Belt(YTGB), China. Boron concentrations range from 0.036–472.4 ppm, and the δ11B values range from -16.0‰ to 13.1‰, indicating the non-marine origin for each geothermal system. We observed a clear binary mixing relationship between the B concentrations and B isotope compositions in Tibet geothermal area. This relationship can be well explained by two sources, i.e., marine carbonate rocks and magmatic rocks, for the Tibet geothermal water. No evidence supports a mantle contribution to B. In addition, we found that the precipitation only plays a dilution role for B of geothermal waters. δ11B values for the precipitation across the southern Tibetan Plateau area range from -6.0‰ to -6.8‰ at least. Due to data scarcity in Yunnan geothermal area, we observed possible different boron sources from the Tibet geothermal system. Comparing it with other geothermal systems in the world, we found that the samples from YTGB have the lowest δ11B values and the largest range of B concentration, which might be related to their special geological background. On the whole, the world geothermal δ11B-Cl/B relation suggests a mixing process between marine and non-marine sources. Additionally, we suggest that B source of B-enriched geothermal waters is mainly from B-enriched crustal country-rocks, instead of mantle.
出处 《Science China Earth Sciences》 SCIE EI CAS 2014年第12期2934-2944,共11页 中国科学(地球科学英文版)
基金 supported by National Natural Science Foundation of China(Grant Nos.41203012,41030317) China Geological Survey(Grant No.1212011085524)
关键词 Yunnan-Tibet geothermal zone Boron isotope geothermal water TRACING 硼同位素 地热区 地球化学过程 地热水 同位素组成 地热系统 起源 海相碳酸盐岩
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