摘要
以6-氯-5,12-萘并萘醌为起始原料,合成了6-(4-甲氧基苯氧基)-5,12-萘并萘醌,通过元素分析、IR、1H NMR和EIMS对其结构进行了表征。研究表明:6-(4-甲氧基苯氧基)-5,12-萘并萘醌可以发生类似于苯氧基萘并萘醌的光异构化反应,trans-form的最大吸收峰出现在395 nm处,而ana-form在450 nm和481 nm处显示出特征双峰,并且只在408 nm处有一个等吸光点。
6-（4-Methoxyphenoxy）-5,12-naphthacenequinone was synthesized using 6-chloro-5,12-naphthacenequinone as the starting material and its structure was confirmed using elemental analysis and the IR, 1 H NMR and MS spectra.The compound exhibited the similar photoisomerization performance with that of phenoxynaphthacenequinone.The transform had an absorption maximum at 395 nm, while the ana-form had two large absorption maxima at 450 nm and 481 nm.Only one isosbestic point was observed at 408 nm.
出处
《广州化工》
CAS
2014年第23期79-80,113,共3页
GuangZhou Chemical Industry
基金
南京化工职业技术学院科研项目(NHKY-2013-8)
