摘要
From the chemical catalysis viewpoint,the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive,in addition to their nanosize channels,sp2-C constructed surfaces,and high thermal/electrical conductivity.This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions,e.g.,hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2,mainly based on recent work carried out in our laboratory.
From the chemical catalysis viewpoint, the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive, in addition to their nanosize channels, sp2-C constructed surfaces, and high thermal/electrical conductivity. This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions, e.g., hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2 mainly based on recent work carried out in our laboratory.
基金
supported by the National Basic Research Program of China(2011CBA00508)
the National Natural Science Foundation of China(20923004)
the Program for Changjiang Scholars and Innovative Research Team in University(IRT1036)
