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An improved method for fluorescence analysis of dissolved organic matter in cave drip water 被引量:1

An improved method for fluorescence analysis of dissolved organic matter in cave drip water
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摘要 An improved synchronous fluorimetric method for the determination of dissolved organic matter in cave drip water, by adding ascorbic acid, is described. The method is based on the redox reaction between ascorbic acid and the electron-withdrawing constituents in dissolved organic matter. The results show that adding ascorbic acid can quench the minor peaks, at 200-300 nm, but does not affect the intensity of the main peaks at 300-500nm. In addition, adding ascorbic acid can maintain relatively high and constant fuorescence intensity over a wide pH range (9-4). An improved synchronous fluorimetric method for the determination of dissolved organic matter in cave drip water, by adding ascorbic acid, is described. The method is based on the redox reaction between ascorbic acid and the electron-withdrawing constituents in dissolved organic matter. The results show that adding ascorbic acid can quench the minor peaks, at 200-300 nm, but does not affect the intensity of the main peaks at 300-500nm. In addition, adding ascorbic acid can maintain relatively high and constant fuorescence intensity over a wide pH range (9-4).
出处 《Frontiers of Earth Science》 SCIE CAS CSCD 2014年第4期595-598,共4页 地球科学前沿(英文版)
基金 Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Nos. 41072262, 41371216, and 41302145), China Postdoctoral Science Foundation (Grant No. 2013M531757). We are grateful to Prof. Philip A. Meyers and James R. Maxwell for language editing that notably improved the manuscript.
关键词 drip water synchronous fluorescence spectro-scopy ascorbic acid PH drip water, synchronous fluorescence spectro-scopy, ascorbic acid, pH
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