期刊文献+

一种新型双氧水电化学传感器设计 被引量:1

Design of a novel electrochemical sensor for detection of hydrogen peroxide
下载PDF
导出
摘要 为满足现场快速、高效检测过氧化氢的需求,建立了一种快速检测食品中过氧化氢的电流型传感器,并对其检测性能进行了评价。该传感器检测下限是1μmol/L(信噪比为3),双氧水浓度在4×10^-6~2.4×10^-4 mol/L范围内与还原峰电流呈线性关系。该传感器重现性高、选择性良好,制作成本低,易于小型化、智能化。 An amperometric sensor for quickly determining hydrogen peroxide in food is developed,and its performance is evaluated with cyclic voltammetry and chronoamperometry.The results show that the current response is increased linearly with the hydrogen peroxide concentration in the range of 4×10^-6—2.4×10^-4mol/L,and the detecting limit can reach 1μmol/L(S/N=3).In addition,the sensor has several advantages as follows:good repeatability and selectivity,simple process,low prime cost and easy industrialization.
出处 《实验技术与管理》 CAS 北大核心 2014年第12期74-76,共3页 Experimental Technology and Management
基金 重庆市高等教育教学改革研究项目(103102) 重庆大学教学改革研究立项(20100249)
关键词 电化学传感器 过氧化氢 卟啉 石墨烯 electrochemical sensor hydrogen peroxide porphyrin graphene
  • 相关文献

参考文献12

  • 1Hurdis E C,Romeyn H.Accuracy of Determination of Hydrogen Peroxide by Cerate Oxidimetry[J].Anal Chem,1954,26:320-325.
  • 2Li J,Tan S N,Ge H.Silica sol-gel immobilized amperometric biosensor for hydrogen peroxide[J].Anal Chim Acta,1996,335(3):137-145.
  • 3Federica Valentini,Lara Cristofanelli,Marilena Carbone,et al.Glassy carbon electrodes modified with hemin-carbon nanomaterial films for amperometric H2O2and NO-2detection[J].Electrochimica Acta,2012,63:37 46.
  • 4Kawamura-Konishi Y,Asano Y,Yamazaki M,et al.Peroxidase activity of an anlibody-ferric porphyrin complex[J].J Mol Catal B:Enzym,1998,4(4):181-190.
  • 5Yu Jiuhong,Ju Huangxian.Amperometric biosensor for hydrogen peroxide based on hemoglobin entrapped in titania sol gel film[J].Analytica Chimica Acta,2003,486(2):209-216.
  • 6Feng D,Wang F,Chen Z.Electrochemical glucose sensor based on one-step construction of gold nanoparticle chitosan composite film[J].Sensors and Actuators B:Chemical,2009,138(2):539-544.
  • 7Ruili Liu,Christian von Malotki,Lena Arnold,et al.Triangular Trinuclear Metal-N4Complexes with High ElectrocatalyticActivity for Oxygen Reduction[J].J Am Chem Soc,2011,133(27):10372-10375.
  • 8Mao M,Zhang D,Sotomura T,et al.Mechanistic study of the reduction of oxygen in air electrode with manganese oxides as electrocatalysts[J].Electrochimica Acta,2003,48(8):1015-1021.
  • 9Yang Hungwei,Hua Muyi,Chen Shilian,et al.Reusable sensor based on high magnetization carboxyl-modified graphene oxide with intrinsic hydrogen peroxide catalytic activity for hydrogen peroxide and glucose detection,Biosensors and Bioelectronics[J].2013,41:172-179.
  • 10Huanbao F A,Wei Yin,Chang Junhou,et al.Photochemical and electrochemical properties of porphyrin dimers containing an anhydride spacer[J].Journal of Coordination Chemistry,2009,62(7):1151-1161.

同被引文献3

引证文献1

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部