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氯化铵催化合成烯胺酮化合物

Catalyzed Synthesis of Enaminones Compounds with Ammonium Chloride
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摘要 以氯化铵为催化剂,在室温下催化伯胺与β-二酮反应,合成标题化合物。该方法收率高、处理方法简单、反应条件温和、环境友好、催化剂可回收,符合绿色化学要求。 β-Enaminoneswere obtained from the reaction between varieties of primary amines with a β-dicarbonyl compoundusing ammonium chloride as a catalyst. This method is high yield,simple process,mild reaction conditions,and environmental friendly;the catalyst could be easily recovered from the reaction mixture. And this reaction complies with the requirement of green chemistry.
出处 《化学试剂》 CAS 北大核心 2015年第1期85-87,90,共4页 Chemical Reagents
基金 安徽省科技攻关计划(12010402084) 安徽省大学生创新训练计划基金资助项目(201310373052) 国家级大学生创新训练计划基金资助项目(201310373032)
关键词 催化 烯胺酮 氯化铵 catalysis β-enaminones ammonium chloride
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  • 1李明,郭维斯,文丽荣,杨华铮.烯胺酮的合成及其在有机合成中的应用[J].有机化学,2006,26(9):1192-1207. 被引量:17
  • 2XIE Guang-yong, LI Yu-xue, SUN Jie, et al. Titanium complexes with β-ketoiminate chelate ligands forethylene polymerization : the significant influence of substituents on structures and catalytic activities [ J ]. lnorg. Chem. Com- mun. ,2009,12 ( 8 ) :796-799.
  • 3RAJIBUL A, NAZNIN A, MOHAMMAD H. Vanadium (IV) acetylacetonate catalyzed stereoselective synthesis of β-enaminoesters and β-enaminones [ J ]. Tetrahedron Lett. ,2013,54(5) :436-440.
  • 4VALDUGA C J, SQUIZANI A, BRAIBANTE H S, et al. The use of K-10/ultrasound in the selective synthesis of unsymmetrical β-enamino ketones [ J ]. Synthesis, 1998,29 (7) :1019-1 022.
  • 5ARCADI A, BIANCHI G, GIUSEPPE S,et al. Gold catal- ysis in the reaction of 1,3-dicarbonyls with nucleophiles [J]. Green Chem. ,2003,5(1) :64-67.
  • 6LIN Jin, ZHANG Li-feng. ZrCl4-Catalyzed efficient syn- thesis of enaminones and enamino esters under solventfree conditions [ J ]. Monatsh Chem. , 2007,138 ( 1 ) : 77-81.
  • 7KHODAEI M M,OSROPOUR A R, OKHAZADEH M. Enamination of β-dicarbonyl compounds catalyzed by CeCl3 ·7H2O at ambient conditions:ionic liquid and sol- vent-free media [ J ]. Synlett,2004,15 ( 11 ) : 1 980-1 984.
  • 8BHOSALE R S,RYAWANSHI P A,GLE S A,et al. Ionic liquid promoted synthesis of β-enamino ketones at room temperature [ J ]. Synlett, 2006,17 ( 6 ) :933-935.
  • 9EPIFANO F, GENOVESE S, CURINI M. Ytterbium tri- flate catalyzed synthesis of β-enaminones [ J ]. Tetrahedron Lett. , 2007,48 ( 15 ) :2 717-2 720.
  • 10BARTOLI G, BOSCO M, LOCATELLI M, et al. Zn (ClO4) 2·6H2O as a powerful catalyst for the conversion of β-ketoesters into β-enamino esters [ J ]. Synlett, 2004, 15 (2) : 239-242.

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