摘要
采用水热法合成出两种新型金属有机骨架化合物MIL-88B（V）和MIL-101（V），通过模拟烟气分析研究其在NH3-scR反应中的催化性能，结果表明，与MIL-101m相比，酸性条件下合成的MIL-88Bm具有更高的结晶度，比表面积和孔体积分别为1332．2m2／g和0．136cmLg-1，280℃时的脱硝效率可以达到70％以上。
Two kinds of new metal organic framework compound MIL-88B （V） and MIL-101 （V） were synthesized by hydrothermal method. Studied its catalytic performance in the NH3-SCR reaction through the simulation of flue gas analysis. The esults showed that compared had with MIL-101 （V）, MIL-88B （V） which synthesized under acidic conditions higher crystallization degrees in 1332.2 m2/g and 0.136 cm3·g-1 respectively, when the temperature was 280℃, denitration efficiency could reach more than 70%.
基金
国家重点基础研究发展计划项目（2011CB936002）.国家自然科学基金面上项目（51178076）,中央高校基本科研业务费专项基金项目（DUT14LK17）
