期刊文献+

预油漆纸用水性氨基/丙烯酸涂料的制备与性能研究 被引量:3

Preparation and Characterization of Waterborne Melamine / Acrylic Coatings for Finish Foil
下载PDF
导出
摘要 以水性羟基丙烯酸作为主要成膜物质,三聚氰胺树脂作为固化剂,加入多种助剂配制预油漆纸用水性氨基/丙烯酸涂料。研究表明:当m(氨基)∶m(丙烯酸乳液)=0.27∶1时,在140℃下烘烤40 s形成的涂膜的耐干热性、耐湿热性、铅笔硬度以及耐化学品性等都达到了相关标准要求。用傅里叶变换红外光谱(FT-IR)研究反应前后氨基/丙烯酸涂料的结构变化,用差示扫描量热法(DSC)和热重法(TGA)分析涂膜的热性能。 Waterborne melamine/acrylic coatings for finish foil were prepared by using nydroxyl-functional acrylic emulsion as the main film forming substance and melamine resin as the curing agent as well as several additives. The results showed that the properties ( e.g., dry heat resistance, wet heat resistance, pencil hardness, and chemical resistance, etc.) of the cured film met the standard requirements when the mass ratio of melamine/acrylic emulsion was 0. 27 : 1 and the film was cured at 140℃ for 40 s. The structure of melamine/acrylic coatings during the curing process was studied by Fourier transform infrared (FT-IR) spectrosco- py. Thermal gravity analysis (TGA) and differential scanning calorimetry (DSC) techniques were also used to analyze the thermal properties of the cured film.
出处 《涂料工业》 CAS CSCD 北大核心 2015年第2期17-22,共6页 Paint & Coatings Industry
关键词 丙烯酸 三聚氰胺 水性涂料 烘烤 预油漆纸 acrylic melamine waterborne coating baking finish foil
  • 相关文献

参考文献8

  • 1TAENGHOM T, PAN Q M, REMPEL G L,et al. Synthesis and characterization of nano-sized poly [ ( butyl acrylate) - co- ( methyl methacrylate) -co- ( methacrylic acid) ] latex via differential microemulsion polymerization [ J ]. Colloid and Polymer Science, 2013, 291 (6) : 1365-1374.
  • 2WANG C C, LIN G, PAE J H, et al. Novel synthesis of carboxy-functional soybean acrylic-alkyd resins for water- reducible coatings [ J ]. Journal of Coatings Technology, 2000, 72(904): 55-61.
  • 3周新华,涂伟萍,胡剑青.Preparation and Characterization of Two-component Waterborne Polyurethane Comprised of Water-soluble Acrylic Resin and HDI Biuret[J].Chinese Journal of Chemical Engineering,2006,14(1):99-104. 被引量:50
  • 4AZNAR A C, PARDINI O R, AMALVY J I. Glossy topcoat exterior paint formulations using water-based polyu- rethane/acrylic hybrid binders [ J ]. Progress in Organic Coatings, 2006, 55( 1):43-49.
  • 5RAMEZANZADEH B, MORADIAN S, TAHMASEBI N. et al. Studying the role of polysiloxane additives and nano-SiO2 on the mechanical properties of a typical acrylic/mela- mine clearcoat[ J]. Progress in Organic Coatings, 2011, 72 (4) : 621-631.
  • 6SHARMIN E, IMO L, ASHRAF S M, et al. Acrylic-mela- mine modified DGEBA - epoxy coatings and their anticorrosive behavior [ J ]. Progress in Organic Coatings, 2004, 50(1) : 47-54.
  • 7HAN R L, ZhANG Y F. Studies on performance of cured water - borne melamine - acrylic emulsion coatings [ J ]. Journal of Adhesion Science and Technology, 2011, 25 (8) : 883-892.
  • 8WICKS Z W, JONES F N, PAPPAS S P, et al. Organic coatings science and technology[ M ] .2 nd edition. NewJer- sey: willy, 2001.

二级参考文献17

  • 1Yang,W.P.,"Thermal and mechanical properties of waterborne polyurethanes",Polym.Mater.Sci.Eng.,66,216-217 (1992).
  • 2Kim,B.K.,Kim,T.K.,Jeong,H.M.,"Aqueous dispersion of polyurethane anionomers from H12MDI/IPDI,PCL,BD,and DMPA",J.Appl.Polym.Sci.,53,371-378 (1994).
  • 3Valentino,J.T.,Thomas,M.E.,Coughlin,R.D.,"Synthesis and coatings properties of novel water-borne polyurethane dispersions",Polym.Mater.Sci.Eng.,73,99-101 (1995).
  • 4Dvorchak,M.J.,"Using high performance two-compoment waterborne polyurethane wood coatings",J.Coat.Technol.,866,47-52 (1997).
  • 5Coogan,R.G.,"Post-crosslinking of water-borne urethanes",Prog.Org.Coat.,32,51-63 (1997).
  • 6Kahl,L.,Bock,M.,"Waterborne two-component PU clear coats for automotive coatings:Development of raw materials and mixing technology",In:Proceeding of 3rd Nurnberg congress,Nurnburg,Germany (1995).
  • 7O'Connor,J.M.,Chen,A.T.,Blackwell,R.S.,Morgan,M.J.,"Two-component waterborne polyurethane coatings based on low viscosity hydrophobic polyisocyanates",In:Proc.24th Waterborne,High Solids and Powder Coatings Symp.,New Orleans,LA (1997).
  • 8Fiori,D.E.,"Two-component water reducible polyurethane coatings",Prog.Org.Coat.,32,65-71 (1997).
  • 9Renk,C.A.,Schwartz,A.J.,"Fast drying,ultra low volatile org.compd.(VOC),two-component waterborne polyurethane coatings for the wood industry",In:Proceedings of the Waterborne High-solids Powder Coating Symposium,New Orleans,LA (1995).
  • 10Mosbach,J.,Laas,H.J.,Kubitza,W.,"Polyisocyanate mixtures,processes for their production and their use as binders for coating compositions or as reactants for compounds reactive to isocyanate groups or carboxyl groups",U.S.Pat.,5098983 (1992).

共引文献49

同被引文献15

引证文献3

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部