期刊文献+

锂离子电池铜集流体表面集电结构加工及性能研究

Manufacturing Process and Performance Analysis of Copper Current Collector with Micro-columnar Structures for Lithium-ion Battery
下载PDF
导出
摘要 铜集流体的导电性能对锂离子电池的容量和循环性能有着较大的影响。采用电火花线切割加工出三种微柱状结构表面的铜片,并在铜片表面涂布五组不同黏度的浆料制作成极板,再用五组不同的烘干温度烘干,烘干后将极板组装成测试体,通过测试电路测试其电阻。研究发现,在浆料成分和配比固定不变的情况下,具有微柱状表面结构的铜集流体的导电性能比光滑表面结构的铜集流体的导电性能提高了约8%,而浆料黏度为2900 MPa·s、3500 MPa·s,干燥温度为70℃制得的负极板的导电性能最好。 The conductivity of copper current collector has a greater impact on the capacity and cycling performance of lithium-ion batteries. In this study,copper sheets with three kinds of micro-columnar surface structures which are machined by using the WEDM( Wire electrical discharge machining) are coated with slurry of five different viscosities and then dried with five different temperatures respectively. Consequently,the plates are assembled to the test body,whose resistance is detected with the test circuit. The results reveal that when the composition and ingredient of slurry are fixed,the conductive property of the copper current collector with micro-columnar surface structures is improved by 8 %,compared with those with smooth surface. And the conductivity of the negative electrode plate is the best when the viscosity of the slurry is at 2900 mpa·s or 3500 mpa·s,and the drying temperature is at 70 ℃.
作者 徐培杰
出处 《机械制造与自动化》 2015年第1期70-75,共6页 Machine Building & Automation
关键词 锂离子电池 铜集流体 电火花线切割加工 导电性能 lithium-ion battery copper current collector WEDM conductivity
  • 相关文献

参考文献15

  • 1GAO,B.,SINHA,S,FLEMING,L,et al.Alloy formation in nanostructured silicon[J].Adv.Mater.2001,13(11):816-819.
  • 2BEATTIE,S D,LARCHER,D.,MORCRETTE,M.,et al.Si electrodes for Li-ion batteries-A new way to look at an old problem[J].J.Electrochem.Soc.,2008,155(2):A158-A163.
  • 3KASAVAJJULA,U.,WANG,C.,APPLEBY,A.J..Nanoand bulk-silicon-based insertion anodes for lithium-ion secondary cells[J].J.Power Sources,2007,163(2):1003-1039.
  • 4RANGANATH TEKI,MONI K.DATTA,RAHUL KRISHNAN,et al.Nanostructured Silicon Anodes for Lithium Ion Rechargeable Batteries[J].Small,2009,5(20):2236-2242.
  • 5H.-C.Shin,J.Dong,M.Liu.Nanoporous Structures Prepared by an Electrochemical Deposition Process[J].2003,15(19):1610-1614.
  • 6Heon-Cheol Shin,Meilin Liu.Copper Foam Structures with Highly Porous Nanostructured Walls[J].Chem.Mater..2004,16(25):5460-5464.
  • 7Tao Jiang,Shichao Zhang,Xinping Qiu,Wentao Zhu,Liquan Chen.Preparation and characterization of tin-based three-dimensional cellular anode for lithium ion battery[J].Power Sources.2007,166(2):503-508.
  • 8周震涛,严燕,潘慧铭.锂离子电池集流体的表面处理方法[P].中国专利:00117142.9,2000-6-8.
  • 9Ki-Lyoung Lee,Ju-Young Jung,Seung-Won Lee,Hee-Soo Moon,Jong-Wan Park.Electrochemical characteristics of a-Si thin film anode for Li-ion rechargeable batteries[J].Power Sources.2004,129(2):270-274.
  • 10Young-Lae Kim,Yang-Kook Sun,Sung-Man Lee.Enhanced electrochemical performance of silicon-based anode material by using current collector with modified surface morphology[J].Electrochimica Acta.2008,53(13):4500-4504.

二级参考文献47

  • 1王强,范雪荣,杨秀娟.乳化剂对浆液粘度的影响分析[J].棉纺织技术,2005,33(10):9-11. 被引量:2
  • 2左朋建,尹鸽平.锂离子蓄电池硅基负极材料的研究[J].电源技术,2006,30(4):334-338. 被引量:4
  • 3何细华,左正忠,杨汉西.电沉积泡沫铜[J].材料保护,1996,29(11):12-14. 被引量:7
  • 4张庆堂,瞿美臻,冯苏宁,等.锂离子电池用复合导电剂浆料制备与性能[C]//第二届中国储能与动力电池及其关键材料学术研讨与技术交流会,成都,2007:29-33.
  • 5MICHEL F,EHRFELD W,KOCH O,et al.EDM for micro fabrication-technology and applications[C]//Proceedings of Int.Seminar on Precision Engineering and Micro Technology,Aachen,Germany,c2000:127-139.
  • 6KOCH O,EHRFELD W,MICHEL F,et al.Recent progress in micro-electro discharge machining-Part 1:Technology[C]//Proceedings of The 13th Int.Symp.on Electro Machining,Spanish,c2001:154-163.
  • 7LIAO Y S,WOO J C.The effect of machining settings on the behavior of pulse trains in the WEDM process[J].J.Mater.Process.Technol.,1997,71(23):433-439.
  • 8PURI A B,BHATTACHARYYA B.An analysis and optimization of the geometrical inaccuracy due to wire lag phenomenon in WEDM[J].International Journal of Machine Tools & Manufacture.2003,43(8):151-159.
  • 9Li, H.; Huang, X. J.; Chen, L. Q.; Wu, Z. G.; Liang, Y. Electrochem. Solid-State Lett., 1999, 2(11): 547.
  • 10Wachtler, M.; Winter, M.; Besenhard, J. O. J. Power Sources, 2001, 94:189.

共引文献20

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部