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Pt@CF复合催化剂对甲醇的电催化氧化

Pt/Carbon nanofiber catalyst for methanol electro-oxidation
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摘要 在碳纤维(Carbon Fiber,CF)表面,采用电沉积方法沉积纳米Pt,形成Pt@CF复合催化剂,用于甲醇的直接电催化氧化。利用金相显微镜对沉积Pt前后的Pt@CF复合催化剂形貌进行了表征。最后,系统地应用电化学方法分析了催化剂的稳定性、甲醇浓度、电位扫描速度和电位扫描范围对催化剂电催化氧化甲醇性能的影响。 The Pt@ CF complex catalysts obtained by electrtodepositing nano -Pt onto carbon fiber (CF), were used for the direct electric catalytic oxidation of methanol. The morphologys of bare CF and Pt@ CF catalyst were characterized by metallographic mi- croscope. At last, the influence of some parameters such as methanol concentration, potential scanrates, and switching potential on itsox- idation as well as long - term stability of the modified electrodehave studied by electrochemical methods.
出处 《新余学院学报》 2015年第1期1-4,共4页 Journal of Xinyu University
基金 国家自然科学基金资助项目<基于仿生铜酶的有机/无机复合膜电极的制备及其催化性能>(51263021) <聚合诱导相分离法原位生长可控结构碳催化层及其DSC光电性能优化理论>(51162025) <基于p-NiO/CH3NH3PbI3/n-ZnO简易三明治结构钙钛矿太阳电池的界面调控与性能优化>(51462035)) 江西省自然科学基金资助项目<Cd Se/TiO2纳米耦合体的自组装及其性能研究>(20141521050002)
关键词 纳米Pt 碳纤维 直接甲醇燃料电池 电催化活性 nano - plainum Carbon fiber DMFE electrocatalytic activity
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参考文献22

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