6-乙酰基-1,1-双二茂铁基丁烷与格氏试剂的反应及其产物的研究

Studies on the reaction of 6-Acetyl-1,1-bisferrocenylbutane with Grignard reagent

本文通过6-乙酰基-1,1-双二茂铁基丁烷与甲基格氏试剂和苯基格氏试剂的反应,得到四种新的反应产物,并利用元素分析,红外光谱,核磁共振氢谱等测试手段对各反应产物进行了表征。通过条件实验确定了最佳反应原料比例,并对两种格氏试剂的反应及其产物进行了讨论。

In this paper, four new compounds were nylbutane with methyl grignard reagent and phenyl obtained from the reaction of 6-Acetyl-1, 1-bisferroce- grignard reagent. These new compounds were characterized by IR spectrum, elemental analysis, 1HNMR spectra . The best reaction condition was confirmed and the reactions of these two kinds of grignard reagent were discussed further more.