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43~17ka川东北石笋^234U/^238U变化及其意义初探 被引量:3

A Primary Study on Speleothem 234U/238U Variations in Northeast Sichuan, Central China during 43~17ka
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摘要 铀(U)是自然界中最重的天然元素.U的价态随氧化-还原条件的变化而变化:在还原环境下多形成难溶于水的+4价铀离子沉淀[2]而在氧化环境中多形成易溶于水的+6价铀酰离子[UO2]2+随溶液迁移[2],并易与碳酸根离子(CO32-)、磷酸根离子(PO43-)和氟离子(F-)形成络合离子[1].岩溶地下水由于具有较高的CO2分压(pCO2)和pH值,铀酰离子主要以碳酸根离子络合态的形式存在[2.3].在表生环境下,土壤氧化还原状态(Eh)与土壤水分含量密切相关,水分含量降低有利于氧化环境形成和土壤Eh上升,因而有利于U的迁移.
出处 《第四纪研究》 CAS CSCD 北大核心 2015年第1期240-241,共2页 Quaternary Sciences
基金 国家自然科学基金项目(41473093和40973009)和中国科学院黄土与第四纪地质国家重点实验室开放基金项目(批准号:SKLLQG1431)共同资助
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  • 10董进国.湖北三宝洞石笋生长速率及其古气候意义[J].第四纪研究,2013,33(1):146-154. 被引量:11

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