摘要
以1,10-菲啰啉为起始原料,经溴代、氧化、Suzuki偶联等反应合成了新型亲脂性菲啰啉衍生物——3,8-二(4-联苯基)-5,6-二(十二烷氧基)-1,10-菲啰啉(1),总收率11.24%,其结构经1H NMR,13C NMR和MALDITOF-MS表征。自组装性能研究结果表明,1的自组装体呈规整的微米球状结构。
A novel lipophilic phenanthroline derivative,3,8-di[(1,1'-biphenyl)-4-yl]-5,6-bis(dodecyloxy)-1,10-phenanthroline(1) in overall yield of 11. 24%,was synthesized by bromination,oxidation and Suzuki- coupling reaction from 1,10-phenanthroline. The structure was characterized by ^1 H NMR,^13 C NMR and MALDI-TOF-MS. The self-assembly properties of 1 were investigated. The results showed that 1 assemble into uniform micro-spheres.
出处
《合成化学》
CAS
CSCD
2015年第2期124-126,共3页
Chinese Journal of Synthetic Chemistry
基金
教育部博士点基金资助项目(20120075120017
20120075110001)
关键词
菲啰啉衍生物
亲脂性
合成
自组装性能
phenanthroline
lipophilic
synthesis
self-assembly property