摘要
概述了烯烃基碳硅氧烷树枝状大分子单体的结构,介绍了层级为1和层级为2的烯烃基碳硅氧烷大分子单体的合成方法及结构表征,以及烯烃基碳硅氧烷树枝状大分子单体在有机聚合物改性及化妆品领域的应用,如:与有机单体溶液共聚制备有机硅改性共聚物、与丙烯酸酯单体乳液共聚制备有机硅改性丙烯酸酯乳液、与长链烷基丙烯酸酯共聚制备化妆品成膜剂、与甘油或木糖醇共改性制备亲水性有机硅交联共聚物等。
The paper summarizes structure of dendritic macromolecular monomer of olefin-based carbon siloxane,introduces the synthetic method and structural characterization of level 1 and level 2 of olefin-based carbon siloxane macromolecular monomer,and discusses the applications of dendritic macromolecules monomer of carbon olefins siloxane,such as the silicone modified copolymer made from the copolymerization of organic monomer solution,and silicone modified acrylate emulsion made from the copolymerization of acrylic ester monomer emulsion,the cosmetics film-forming made from the copolymerization of a long chain alkyl acrylate,as well as the hydrophilic silicone crosslinked copolymer modified with glycerin or xylitol.
出处
《有机硅材料》
CAS
2015年第1期61-68,共8页
Silicone Material
关键词
碳硅氧烷
树枝状
大分子单体
M支链
烯烃基
硅氢基
化妆品
carbon siloxane
dendritic
macromolecular monomer
M branched chain
olefin
silicon hy-drogen