期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

含咪唑类聚合物的电化学合成及电致变色 被引量：1

Imidazole Containing Polymers Electrochemical Synthesis and Electrochromic
下载PDF
导出
摘要 本实验通过电化学方法研究合成了一种不同的新型共轭聚合物PM1,相应的单体通过Still偶联反应合成了聚合物单体M1,合成得到的聚合物,具有多色电致变色现象,合成得到的电致变色材料亦被详细的表征.循环伏安法和紫外-可见光谱法被用来揭示聚合物膜的光电性能. In this experiment,the synthesis of a novel different conjugated polymer PM1 was studied by electrochemical methods,monomer monomer M1 was synthesized by Still coupling reaction,synthetic polymers are obtained,with multicolor electrochromic phenomenon,the synthesized electrochromic materials was also investigated.Photoelectric properties of visible spectroscopy of cyclic voltammetry and UV-was used to reveal the polymer film.
作者 张军红 魏西莲 赵金生 郝静敏 刘洋洋 闫娜娜
机构地区 聊城大学化学化工学院
出处 《聊城大学学报（自然科学版）》 2014年第4期37-41,共5页 Journal of Liaocheng University:Natural Science Edition
基金 山东省教育厅计划(J12LD13) 聊城大学博士基金项目(31805) 聊城大学大学生科技文化创新项目(SF2013124 SF2012068)
关键词 导电聚合物 电致变色 光学表征 conductive polymer electrochromic characterization
分类号 O657.11 [理学—分析化学]
  • 相关文献

参考文献12

  • 1Lakshmi A,Anandha R.J,Gopu G,et al.Electrochemical,electrochromicbehaviour and effects of supporting electrolyte on nanothin film of poly(3,4-ethylenedioxy thiophene)[J].Electrochimica Acta,2013,92(1):452-459.
  • 2Ozelcaglayana A C,Sendura M,Akbasoglua N,et al.Synthesis and electrochemical properties of a novel benzimidazole derivative as the acceptor unit in Donor-Acceptor-Donor type polymers[J].Electrochim Acta,2012,67:224-229.
  • 3Hu B,Zhang Y J,Lv X J,et al.Electrochemical and electrochromic properties of two novel polymers containing carbazole and phenylmethanone units[J].Journal of Electroanalytical Chemistry,2013,689:291-296.
  • 4Pinhey J T,Roche E G.The chemistry of organolead(IV)tricarboxylates.Synthesis and electrophilic heteroarylation reactions of 2-and 3-thienyl-,and 2-and 3-furyl-lead tricarboxylates[J].Journal of the Chemical Society,Perkin Transactions 1,1988,8:2 415-2 421.
  • 5Bundgaard E,Kreb F C.A comparison of the photovoltaic response of head-to-head and head-to-tail coupled poly{(benzo-2,1,3-thiadiazol-4,7-diyl)-(dihexyl[2,2’]dithiophene-5,5’-diyl}[J].Polym Bull,2005,55(3):157-164.
  • 6Kim E,Kim M,Kim K.Diarylethenes with intramolecular donor-acceptor structures for photo-induced electrochemical change[J].Tetrahedron,2006,62(29):6 814-6 821.
  • 7李永舫.导电聚合物的电化学性质[J].复旦学报（自然科学版）,2004,43(4):468-476. 被引量：33
  • 8Raimundo J M,Blanchard P,Frere P,et al.Push-pull chromophores based on 2,2′-bi(3,4-ethylenedioxythiophene)(BEDOT)π-conjugating spacer[J].Tetrahedron Letters,2001,42(3):1 507-1 510.
  • 9Lu G.W,ShiG Q.Electrochemical polymerization of pyrene in the electrolyte of boron trifluoride diethyl etherate containing trifluoroacetic acid and polyethylene glycol oligomer[J].J Electroanal Chem,2006,586:154-160.
  • 10Maoi K,Sakai,Ogano S,etal.Improment of battery performance of lithium batterries assembled with a polypyrrolecathodformedectrochemically with the aid of a nitrile rubber insulalting film[J].J Power Source,1987,20:203-237.

二级参考文献37

  • 1Shirakawa H, Louis E L, MacDiarmid A G, et al, Synthesis of electrically conducting organic polymers: Halogen derivatives of polyacetylene[J], J Chem Soc Chem Commun, 1977: 578-580.
  • 2Eckhardt H, Shacklette L W, Jen K Y, et al, The electronic and electrochemical properties of poly(phenylene vinylene) and poly(thienylene vinylene): An experimental and theoretical study[J]. J Chem Phys, 1989, 91: 1303-1315.
  • 3Li Y F, Qian R Y. On the nature of redox processes in the cyclic voltammetry of polypyrrole in aqueous solutions[J]. J Electroanal Chem, 1993, 362:267-272.
  • 4Li Y F, Liu Z F. Electrochemical quartz crystal microbalance studies on the two reduction processes of conducting polypyrrole nitrate films in aqueous solutions[J]. Synth Met, 1998, 94: 131-133.
  • 5Li Y F, Qian R Y. Studies on the electrode kinetics of polypyrrole in aqueous solutions by ac impedance measurement[J]. Synth Met, 1994, 64: 241-245.
  • 6Bandey H L, Cremins P, Garner S E, et al, In-situ electron-spin-resonance study of n-doping andp-doping of polythiophene[J]. J Electrochem Soc, 1995, 142: 2111 -2118.
  • 7Zhou Q, Zhuang L, Lu J T. In situ ESR studies over wide temperature range for conducting polymers[J]. Electrochem Commun, 2002: 4:733-736.
  • 8Kudoh Y. Properties of polypyrrole prepared by chemical polymerization using aqueous solution containing Fe2(SO4)3 and anionic surfactant[J]. Synth Met, 1996, 79: 17-22.
  • 9Shimidzu T, Ohtani A, Iyoda T, et al. Charge-controllable polypyrrole/polyelectrolyte composite membranes, Part II. Effect of incorporated anion size on the electrochemical oxidation-reduction process[J]. J Electroanal Chem, 1987, 224: 123-135.
  • 10Li Y F, Qian R Y. Effect of anion and solution pH on the electrochemical behavior of polypyrrole in aqueous solution[J]. Synth Met, 1989, 28: c127-c132.

共引文献32

引证文献1

二级引证文献3

聊城大学学报（自然科学版）
2014年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部