摘要
A novel porous aromatic framework, PAF-52, was obtained via the polymerization of tetrahedral mono- mer tetrakis(4-cyanodiphenyl) methane(TCDPM) with the aid of a facile ionothermal method. PAF-52 has a surface area of 1159 m2/g(BET), and shows a considerable high separation ability of CO2 in N2 or CH4 respectively at room temperature, using gas-chromatography experiments as evidence,
A novel porous aromatic framework, PAF-52, was obtained via the polymerization of tetrahedral mono- mer tetrakis(4-cyanodiphenyl) methane(TCDPM) with the aid of a facile ionothermal method. PAF-52 has a surface area of 1159 m2/g(BET), and shows a considerable high separation ability of CO2 in N2 or CH4 respectively at room temperature, using gas-chromatography experiments as evidence,
基金
Supported by the National Natural Science Foundation of China(No.20831002) and the National Key Basic Research and Development Program of China(No.2010CB63100).