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新型功能材料钨离子液体的合成及表征 被引量:2

Synthesis and Characterization of Tungsten Ionic Liquid as New Functional Material
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摘要 合成了一系列由阳离子N-甲基咪唑和阴离子WO2-4组成的新型离子液体:2-(1-丙基-3-甲基-咪唑)钨酸盐(记为[C3mim]2[WO4])、2-(1-丁基-3-甲基-咪唑)钨酸盐(记为[C4mim]2[WO4])、2-(1-戊基-3-甲基-咪唑)钨酸盐(记为[C5mim]2[WO4])、2-(1-己基-3-甲基-咪唑)钨酸盐(记为[C6mim]2[WO4])。对上述离子液体进行了表征以及结构验证。 A series of new ionic liquids were synthesized composed of WO2-4 anion and N-methylimidazole cation, including 2- (1-propyl-3-methyl-imidazole) tungstate ( [C3 mim]2 [WO4 ] ), 2- ( 1-butyl-3-methyl-imid azole ) tungstate ( [-C4 mim]2 [WO4 ] ), 2-(1-pentyl-3-methyl-imidazole) tungstate ( [-C5 mim]2 [-WO4 ) and 2-(1-hexyl-8-methyl-imidazole) tungstate ([C6 mim]2 [WO4]). And then the above ionic liquids were char acterized and verified for their structure.
出处 《稀有金属与硬质合金》 CAS CSCD 北大核心 2014年第6期20-22,45,共4页 Rare Metals and Cemented Carbides
基金 国家科技支撑计划(2012BAF03B02) 国家自然科学基金(21373005,21471073) 辽宁省自然科学基金(201202084)
关键词 离子液体 合成 表征 tungsten ionic liquid synthesis characterization
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