摘要
采用低温固相合成法制备了3种有机/无机杂合物(CnH2n+1NH3)2NiCl4(n=4,8,12),通过元素分析、X射线粉末衍射、红外光谱和紫外-可见吸收光谱对杂合物进行了表征.实验结果表明,利用低温固相合成法可成功制备杂合物(CnH2n+1NH3)2NiCl4(n=4,8,12),3种产物均具有明显的层状结构且分别属于单斜晶系、六方晶系和正交晶系.
The organic/inorganic hybrids （Cn H2 n ＋ 1 NH3 ）2 NiCl4 （n = 4 ,8 ,12） were synthe‐sized by a low temperature solid state reaction .The hybrids were characterized by elemental a‐nalysis ,X‐ray powder diffraction ,infrared spectrometry and UV‐Vis absorption .The results indicate that （Cn H2 n ＋ 1 N H3 ）2 NiCl4 （n = 4 ,8 ,12） were obtained successfully via a solid state reaction at low temperature and all the products have typical layered structures ; （Cn H2 n ＋ 1 N H3 ）2 NiCl4 （n = 4 ,8 ,12） can be indexed as monoclinic system ,hexagonal system and ortho‐rhombic system ,respectively .
出处
《化学研究》
CAS
2015年第1期26-29,共4页
Chemical Research
