摘要
A simple and efficient method for the synthesis of ultrasmall Pd nanoclusters(NCs) has been developed. The as-obtained Pd NCs displayed uniform size with an average diameter of 1.8±0.2 nm. The ultrasmall Pd NCs and carbon nanotubes(CNTs)-supported Pd NCs also showed outstanding catalytic activity for nitrobenzene reduction and Suzuki coupling reactions. Notably, the reactions were conducted under mild conditions with high yield and selectivity.
A simple and efficient method for the synthesis of ultrasmall Pd nanoclusters（NCs） has been developed. The as-obtained Pd NCs displayed uniform size with an average diameter of 1.8±0.2 nm. The ultrasmall Pd NCs and carbon nanotubes（CNTs）-supported Pd NCs also showed outstanding catalytic activity for nitrobenzene reduction and Suzuki coupling reactions. Notably, the reactions were conducted under mild conditions with high yield and selectivity.
基金
supported by the National Natural Science Foundation of China(20871112,21072001,21201001,21372006)
the Chang Jiang Scholars Program
the Scientific Research Foundation for Returning Overseas Chinese Scholars
Ministry of Education and Ministry of Human Resources and Social Security,Anhui Province International Scientific and Technological Cooperation Project
Anhui Provincial Natural Science Foundation(1208085QB25)
the 211 Project of Anhui University
