摘要
将巯基-端烯/炔点击反应应用于制备潜在的液晶显示材料、液晶半导体材料.即在室温条件下,催化量的安息香二甲醚作为光引发剂,365 nm波长紫外光辐照正十二硫醇和端炔/烯三联苯、联苯化合物4 h即可以合成60%左右产率的目标产物.化合物的结构通过核磁共振氢谱、红外光谱和元素分析进行表征;目标化合物的介晶性经差示扫描量热法、偏光显微镜和变温X射线衍射法测试.结果显示含三联苯刚性核的化合物2呈现多个晶态和多个近晶相.
This paper successfully used thiol-ene and thiol-yne click reaction in the preparation of calamitic liquid crystalline materials which will be applied to display or semiconductor materials. We used catalytic amount of 2,2-dimethoxy-2-phenylacetophenone as the photoinitiator and 365 nm wavelength UV irradiation of thiol-ene or thiol-yne four hours to obtain a moderate yield at room temperature. Target compounds were characterized by1 H NMR,FTIR and EA characterization. Mesomorphism of the target compound was confirmed by differential scanning calorimetry( DSC),polarized light microscopy( POM) and X-ray diffraction( XRD) at different temperatures. The results show that multiple crystalline states and smectic liquid crystalline states can be observed in terphenyl compound 2.
出处
《四川师范大学学报(自然科学版)》
CAS
北大核心
2015年第1期101-108,共8页
Journal of Sichuan Normal University(Natural Science)
基金
国家自然科学基金(51273133)
四川省应用基础基金(2010JY0124)
四川省教育厅青年基金(11ZB075)资助项目
关键词
光化学
点击反应
液晶
近晶相
三联苯
photochemistry
click reaction
liquid crystal
smetic phase
terphenyl