摘要
环氧树脂具有优良的热稳定性、电绝缘性能和物理、机械性能,但其固化后较脆、不耐冲击和容易应力开裂。本文提出在合成一种新型柔性环氧树脂固化剂,通过与环氧树脂固化反应后提高环氧树脂韧性的改性思路,达到提高环氧树脂韧性而不降低树脂固化物的强度和模量的目的。研究结果表明,当柔性固化剂的用量为质量百分含量在10%~15%之间时韧性达到最大。对于使用柔性固化剂固化环氧树脂,当柔性固化剂的用量为环氧树脂质量百分含量的10%时达到最大值,冲击韧性和断裂韧性分别比纯环氧树脂提高了33.3%和96.3%。柔性固化剂的用量为环氧树脂质量百分含量的10%时,在-50℃时冲击韧性大小为19.5k J·m^-2,而此时纯环氧树脂的冲击韧性仅为7.96k J·m^-2。
This paper presents the synthesis of a new type of flexible epoxy curing agent and an approach to improve the toughness of epoxy resin by curing without reducing the strength and modulus of the resin-cured material.The results show that the degree of toughness reaches maximum values when the flexible curing agent is applied at weight percentages（ wt. %） between 10% and 15%. When the amount of flexible curing agent added to epoxy resin weight is 10 wt. %,the impact toughness and fracture toughness increases by 33. 3% and 96. 3%,respectively,compared with the pure epoxy resin. When the amount of flexible curing agent added to epoxy is 10 wt. %,the resulting impact toughness of the material is 19. 5k J·m^-2at-50℃,the impact toughness of pure epoxy resin is only7. 96 k J·m^-2.
出处
《合成材料老化与应用》
2015年第1期27-31,共5页
Synthetic Materials Aging and Application
关键词
环氧树脂
分子合成
机械性能
动力学
断裂韧性
增韧机理
epoxy resin
molecular synthesis
mechanical properties
kinetics
fracture toughness
toughening mechanism
