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新型超支化环氧丙烯酸酯的合成及表征 被引量:1

Synthesisand and Characterization of a New Structure Hyperbranched Epoxy Acrylate
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摘要 本文以双酚A与异氰尿酸三缩水甘油脂通过质子转移聚合法成功制备了超支化环氧树脂,采用端基修饰的方法合成了一种新型的超支化环氧丙烯酸酯,通过FTIR对产物结构进行了表征,并对其合成条件进行了探究。测试了超支化环氧丙烯酸酯的紫外-可见光谱及光固化行为。 Hyperbranched epoxy resin (HEP) was synthesized by proton transfer polymerization. And a novel structure hyperbranched epoxy acrylate (PEA) containing both epoxy group and carbon - carbon double bond was synthesized by acrylic modified the HEP. Tile structures of the polymer were characterized by FT - IR. The extent of the reaction was monitored by controlling the molar ratio and measuring the acid value. Hyperbranehed polymers were characterized by UV - Vis spectra.
出处 《山东化工》 CAS 2015年第5期3-5,共3页 Shandong Chemical Industry
基金 辽宁省博士启动资金(20111066)
关键词 超支化聚合物 超支化环氧树脂 紫外光固化 hyperbranched polymers hyperbranched epoxy resin UV curing
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