期刊文献+

稀土异戊橡胶在全钢载重子午线轮胎胎面中的应用 被引量:4

Application of Neodymium Isoprene Rubber in Tread of Truck and Bus Radial Tire
下载PDF
导出
摘要 研究稀土异戊橡胶(Nd-IR)在全钢载重子午线轮胎胎面中的应用。根据傅里叶转换红外光谱和核磁共振谱,Nd-IR的顺式1,4-结构摩尔分数大于0.98且不含有反式1,4-结构,所有的序列单元与天然橡胶(NR)一样,均以"头-尾"方式键接。Nd-IR的物理性能与NR相差不大,将其以60%的比例替代NR用于全钢载重子午线轮胎胎面胶,加工性能不受影响,轮胎的各项性能均合格,其中耐久性能远高于全NR生产的轮胎。 The application of neodymium isoprene rubber(Nd-IR)in the tread compound of truck and bus radial tire was investigated.Fourier transform infrared(FTIR)spectroscopy and nuclear magnetic resonance(NMR)spectroscopy were carried out to characterize the structure of Nd-IR.The test results showed that the content of cis 1,4-configuration in Nd-IR was above 98%,trans 1,4-configuration could not be detected,and all repeating units of Nd-IR presented " head-to-tail" structure,which was same as natural rubber(NR).The mechanical properties of Nd-IR did not show significant difference with NR.By using Nd-IR to replace 60% of NR by weight in the tread compound of truck and bus radial tire,the processibility of the compound was not affected,the tire performance was qualified,and the endurance performance was much higher.
出处 《轮胎工业》 CAS 2015年第2期93-96,共4页 Tire Industry
关键词 稀土异戊橡胶 微观结构 物理性能 全钢载重子午线轮胎 胎面胶 neodymium isoprene rubber microstructure mechanical property truck and bus radial tire tread compound
  • 相关文献

参考文献9

  • 1Friebe L,Nuyken O,Obrecht W. Neodymium-based Ziegler/ Natta Catalysts and Their Application in Diene Polymeriza- tion[J]. Adv. Polym. Sci. , 2006,204 : 1-154.
  • 2Zhang Z, Cui D, Wang B, et al. Polymerization of 1,3-Conju- gated Dienes with Rare-Earth Metal Precursors[J]. Struct. Bond, 2010,137 : 49-108.
  • 3Oehme A,Gebauer U,Gehrke K. The Influence of the Cata- lyst Preparation on the Homo-and Copolymerization of Buta- diene and Isoprene[J]. Macromol. Chem. Phys. , 1994, 195 (12) :3773-3781.
  • 4Nickaf J B,Burford R P,Chaplin R P. Kinetics and Molecular Weights Distribution Study of Neodymium-catalyzed Poly- merization of 1,3-ButadieneJ]. Polym. Sci. , 1995,33 (7) : 1125-1132.
  • 5长春应用化学研究所.稀土催化合成橡胶文集[M].北京:科学出版社,1980:70-82.
  • 6张杰,华炜,谭金枚,等.钕系均相稀土催化剂、其制备方法及其应用[P].中国:CN102108105A.2009-12-25.
  • 7闫家宾,张玉聚合物物理化学手册[M].北京:中国石化出版社.1995:235-236.
  • 8Khatchaturov A S,Dolinskaya E R,Prozenko L K,et al. 13C NMR Determination of Units Formed by Irregular Addition in Polyisoprene[J]. Polymer,1977,18(9) :871-877.
  • 9Sato H, Ono A, Tanaka Y. Distribution ol Isomeric Structures in Polyisoprenes[J]. Polymer, 1977,18(6) : 580-586.

共引文献1

同被引文献23

引证文献4

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部