摘要
研究稀土异戊橡胶(Nd-IR)在全钢载重子午线轮胎胎面中的应用。根据傅里叶转换红外光谱和核磁共振谱,Nd-IR的顺式1,4-结构摩尔分数大于0.98且不含有反式1,4-结构,所有的序列单元与天然橡胶(NR)一样,均以"头-尾"方式键接。Nd-IR的物理性能与NR相差不大,将其以60%的比例替代NR用于全钢载重子午线轮胎胎面胶,加工性能不受影响,轮胎的各项性能均合格,其中耐久性能远高于全NR生产的轮胎。
The application of neodymium isoprene rubber(Nd-IR)in the tread compound of truck and bus radial tire was investigated.Fourier transform infrared(FTIR)spectroscopy and nuclear magnetic resonance(NMR)spectroscopy were carried out to characterize the structure of Nd-IR.The test results showed that the content of cis 1,4-configuration in Nd-IR was above 98%,trans 1,4-configuration could not be detected,and all repeating units of Nd-IR presented " head-to-tail" structure,which was same as natural rubber(NR).The mechanical properties of Nd-IR did not show significant difference with NR.By using Nd-IR to replace 60% of NR by weight in the tread compound of truck and bus radial tire,the processibility of the compound was not affected,the tire performance was qualified,and the endurance performance was much higher.
出处
《轮胎工业》
CAS
2015年第2期93-96,共4页
Tire Industry
关键词
稀土异戊橡胶
微观结构
物理性能
全钢载重子午线轮胎
胎面胶
neodymium isoprene rubber
microstructure
mechanical property
truck and bus radial tire
tread compound