摘要
The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%–98%.Four stereo‐isomers of the bis‐2,2'‐norbornylidene structure were identified in the dimer fraction,with the(Z)‐anti‐bis‐2,2'‐norbornylidene prevailing over the others.
The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2＇‐norbornylidene structure were identified in the dimer fraction,with the（Z）‐anti‐bis‐2,2＇‐norbornylidene prevailing over the others.
出处
《催化学报》
SCIE
CAS
CSCD
北大核心
2015年第3期268-273,共6页
