摘要
以乙烯为碳源、无负载型铜镍(Cu-Ni)合金为催化剂,采用催化化学气相沉积法(CVD),制备出性能优异的纳米炭纤维(CNF)块体,并考察制备条件对CNF块体的形貌、机械性能及比表面积的影响。结果表明,CNF块体的成形主要依赖于催化剂Cu-Ni的组成、生长温度及生长时间等因素。当Cu-Ni质量比为2∶8、生长温度为580℃时,经3 h制备的CNF块体,其密度、压缩弹性模量、比表面积分别达到0.28g/cm3、1.7KPa和117m2/g。CNF生长初始阶段的形貌观察表明,章鱼状粗纤维和细纤维交织成的三维网络结构是块体成形的主要原因。
Carbon nanofiber(CNF) monoliths with excellent properties were prepared by catalytic chemical vapor deposition,using ethylene(C2H4) and a non-supported Cu-Ni alloy as carbon source and catalyst,respectively.The structure,mechanical properties,and specific surface area of the CNF monoliths were characterized for various preparation conditions.The formation of CNF monoliths mainly depended on the Cu/Ni ratio,growth temperature and time.A CNF monolith synthesized at 580℃ for 3 h from a Cu-Ni catalyst with a Cu/Ni mass ratio of 0.25 exhibited a bulk density of 0.28 g/cm^3,a compressive elastic modulus of1.7 kPa,and a specific surface area of 117 m^2/g.SEM images of the CNF monoliths in the initial growth stage further indicated that they were composed of thick octopus-like nanofibers and thin nanofibers that were interwoven with each other to form a three dimensional CNF network and finally the CNF monolith.
出处
《新型炭材料》
SCIE
EI
CAS
CSCD
北大核心
2015年第1期54-62,共9页
New Carbon Materials
基金
国家自然科学基金(20977028
51172071
51272077)
国家重点基础研究发展规划(973)(2014CB239702)
中央高校基本科研业务费专项基金
上海市优秀技术带头人计划(B类
13XD1424900)~~