摘要
Hydrothermal reactions of two imidazole derivatives (1,3,5-tib = 1,3,5-tris(1H- imidazol- 1 -yl)benzene, 1,4-bimb = 1,4-bis(1 H-imidazol- 1 -ylmethyl)benzene) and the ZnⅡ cations in the presence of oxalic acid (H2ox) afford two coordination polymers, namely, {[Zn(ox)(1,3,5- tib)]·2(H20)}n (1) and [Znl.5(OX)1.5(1,4-bimb)l.5]n (2). Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, and powder X-ray diffraction (PXRD) analyses. Both complexes 1 and 2 are based on the 1D zigzag [Zn(ox)]n chains, and their final structures are controlled by the two different imidazole linkers, which expanded the structure along different directions, finally giving a 3D dia net for 1 and a 2D sql layer for 2. Moreover, the luminescent properties of 1 and 2 have been investigated.
Hydrothermal reactions of two imidazole derivatives (1,3,5-tib = 1,3,5-tris(1H- imidazol- 1 -yl)benzene, 1,4-bimb = 1,4-bis(1 H-imidazol- 1 -ylmethyl)benzene) and the ZnⅡ cations in the presence of oxalic acid (H2ox) afford two coordination polymers, namely, {[Zn(ox)(1,3,5- tib)]·2(H20)}n (1) and [Znl.5(OX)1.5(1,4-bimb)l.5]n (2). Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, and powder X-ray diffraction (PXRD) analyses. Both complexes 1 and 2 are based on the 1D zigzag [Zn(ox)]n chains, and their final structures are controlled by the two different imidazole linkers, which expanded the structure along different directions, finally giving a 3D dia net for 1 and a 2D sql layer for 2. Moreover, the luminescent properties of 1 and 2 have been investigated.
基金
supported by the National Natural Science Foundation of China(20873150)
the Natural Science Foundation of Shandong Province(ZR2010BL012,ZR2010BQ023)