摘要
One new coordination polymer, [Ni（m-bix）（m-BDC）]（1, m-bix = 1,3-bis（imidazol-1-ylmethyl）benzene, m-BDC = 1,3-benzenedicarboxylic acids）, has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The green block crystal of complex 1（C22H18N4Ni O4） belongs to monoclinic system, space group P21/c with a = 10.0418（3）, b = 23.8651（6）, c = 8.7872（2） A, β = 112.333（3）°, V = 1947.88（9）A3, Z = 4, Dc = 1.572 g/cm^3, Mr = 461.11, F（000） = 952, R = 0.0335 and w R = 0.0683 for 2827 observed reflections（I 〉 2σ（I））. Complex 1 exhibits a novel 6-connected 3D sxd type topological framework. The magnetic characterization of complex 1 shows antiferromagnetic coupling exchange.
One new coordination polymer, [Ni（m-bix）（m-BDC）]（1, m-bix = 1,3-bis（imidazol-1-ylmethyl）benzene, m-BDC = 1,3-benzenedicarboxylic acids）, has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The green block crystal of complex 1（C22H18N4Ni O4） belongs to monoclinic system, space group P21/c with a = 10.0418（3）, b = 23.8651（6）, c = 8.7872（2） A, β = 112.333（3）°, V = 1947.88（9）A3, Z = 4, Dc = 1.572 g/cm^3, Mr = 461.11, F（000） = 952, R = 0.0335 and w R = 0.0683 for 2827 observed reflections（I 〉 2σ（I））. Complex 1 exhibits a novel 6-connected 3D sxd type topological framework. The magnetic characterization of complex 1 shows antiferromagnetic coupling exchange.
基金
Supported by the National Natural Science Foundation of China(21371052)
