期刊文献+

海藻酸钠在锂离子电池中的应用 被引量:3

Application of sodium alginate in Li-ion battery
下载PDF
导出
摘要 研究了以海藻酸钠为粘结剂制备锂离子电池的加工特性、倍率放电特性及循环特性;分析了海藻酸钠的机械特性。海藻酸钠薄膜具有较高的弹性模量,较羧甲基纤维素钠和丁苯橡胶复合粘结剂体系提升100%,制备的极片粘结力较羧甲基纤维素钠和丁苯橡胶复合体系提升30%。海藻酸钠制备的锂离子电池化成后,阻抗仅为常规羧甲基纤维素钠和丁苯橡胶复合粘结剂体系锂离子电池的一半,在2 C放电(3.0~4.2 V)的容量提升10%。 The process characteristics,rate discharge capability and cycle performance of Li-ion battery prepared by sodium alginate binder were studied. Mechanical properties of sodium alginate were tested. Elastic modulus of sodium alginate improved 100%compared to sodium carboxymethyl cellulose(CMC) + styrene-butadiene rubber(SBR) system,peel strength of electrode with sodium alginate was improved 30% compared to CMC + SBR system. The electrochemical test showed 2 C rate improved 10%because of lower impedance for cell with sodium alginate.
出处 《电池》 CAS CSCD 北大核心 2015年第1期45-47,共3页 Battery Bimonthly
关键词 海藻酸钠 弹性模量 水性粘结剂 sodium alginate elastic modulus aqueous binder
  • 相关文献

参考文献5

  • 1杨亦轩,李利淼,毛占稳,于瑜.羧甲基纤维素钠在锂离子电池中应用的进展[J].电池,2013,43(5):303-305. 被引量:4
  • 2Bridel J S,Azais T, Morcrette M. Key parameters governing thereversibility of Si/carbon/CMC electrodes for Li-ion batteries [ J ].Chem Mater,2010,22(3) ;1 229-1 241.
  • 3Courtel F M,Niketic S,Dominique D,et al. Water-soluble bindersfor MCMB carbon anodes for lithium-ion batteries [ J ] . J PowerSources,2011,196(4) :2 128 -2 134.
  • 4Li J,Leb D B,Fei^uson P P,ei al. Lithium polyacrylate as a binderfor tin-cobalt-carbon negative electrodes in lithium-ion batteries[J]. Electrochim Acta,2010,55(8) :2 991 -2 995.
  • 5庄全超,徐守冬,邱祥云,崔永丽,方亮,孙世刚.锂离子电池的电化学阻抗谱分析[J].化学进展,2010,22(6):1044-1057. 被引量:115

二级参考文献22

  • 1庄全超,陈作锋,董全峰,姜艳霞,周志有,孙世刚.锂离子电池电解液中甲醇杂质对石墨电极性能影响机制的电化学阻抗谱研究[J].高等学校化学学报,2005,26(11):2073-2076. 被引量:18
  • 2Xie L,Zhao I.The Electrochemical performance of carboxymethyl cellulose lithium as a binding material for anthraquinone cathodes in lithium batteries[J].J Electrochem Soc,2012,159(4):499-505.
  • 3He M,Yuan L X,Huang Y H,et al.Enhanced cyclability for sulfur cathode achieved by a water-soluble binder[J].J Physical Chemistry C,2011,115(31):5 703-5 709.
  • 4Han Z J,Yabuuchi N,Hashimoto S,et al.Cross-linked poly(acrylic acid)with polycarbodiimide as advanced binder for Si/graphite composite negative electrodes in Li-ion batteries[J].ECS Electrochemistry Lett,2012,2 (2):17-20.
  • 5Li J,Leb D B,Ferguson P P,et al.Lithium polyacrylate as a binder for tin-cobalt-carbon negative electrodes in lithium-ion batteries[J].Electrochim Acta,2010,55(8):2 991-2 995.
  • 6Chou S L,Lu L,Wang J Z,et al.The compatibility of transition metal oxide/carbon composite anode and ionic liquid electrolyte for the lithium-ion battery[J].J Appl Electrochem,2011,11 (41):1261-1 267.
  • 7Courtel F M,Niketic S,Dominique D,et al.Water-soluble binders for MCMB carbon anodes for lithium-ion batteries[J].J Power Sources,2011,196(4):2 128-2 134.
  • 8Zuo P J,Yang W G,Cheng X Q,et al.Enhancement of the electrochemical performance of silicon/carbon composite material for lithium ion batteries[J].Ionics,2011,17(1):87-90.
  • 9Lee J H,Paik U,Hackley V A,et al.Aqueous processing of natural graphite particulates for lithium-ion battery anodes and their electrochemical performance[J].J Power Sources,2005,147 (1-2):249-255.
  • 10Leais R B,Timmons A,Mar R E,et al.In situ AFM measurements of the expansion and contraction of amorphous Sn-Co-C films reacting with lithium[J].J Electrochem Soc,2007,154 (3):213-216.

共引文献117

同被引文献18

引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部