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Li[Li_(0.2)Mn_(0.54)Ni_(0.13)Co_(0.13)]O_2/BiPO_4的高循环性能 被引量：4

High cycle performance of Li[Li_(0.2)Mn_(0.54)Ni_(0.13)Co_(0.13)]O_2/ BiPO_4
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摘要 用固相法合成富锂材料Li[Li0.2Mn0.54Ni0.13Co0.13]O2,通过包覆磷酸铋（Bi PO4）对材料进行表面改性,以提高循环稳定性。XRD、SEM及TEM测试结果表明,包覆材料Li[Li0.2Mn0.54Ni0.13Co0.13]O2/Bi PO4的结构与Li[Li0.2Mn0.54Ni0.13Co0.13]O2相比没有发生变化,Bi PO4均匀地包覆在材料表面,包覆层厚度约为10 nm。在2.0~4.8 V充放电,当电流为0.1 C时,制备的Li[Li0.2Mn0.54Ni0.13Co0.13]O2/Bi PO4的首次库仑效率从Li[Li0.2Mn0.54Ni0.13Co0.13]O2的75%提高到83%,以0.2 C循环100次,放电比容量保持在249 m Ah/g。 Lithium rich material Li[Li0. 2Mn0. 54Ni0. 13Co0. 13]O2was prepared by solid-state method,then modified by coating bismuth phosphate（BiPO4） to improve cycle stability. The results of XRD,SEM and TEM tests showed that the structure of coated material Li[Li0. 2Mn0. 54Ni0. 13Co0. 13]O2/ BiPO4 had no change compared to Li[Li0. 2Mn0. 54Ni0. 13Co0. 13]O2. BiPO4 was uniformly coated on the surface of the material with the thickness of 10 nm. When charged-discharged in 2. 0 ~ 4. 8 V,the initial Coulombic efficiency of Li[Li0. 2Mn0. 54Ni0. 13Co0. 13]O2/ Bi PO4 was improved from 75%（Li[Li0. 2Mn0. 54Ni0. 13Co0. 13]O2） to 83% when the current was 0. 1 C,the specific discharge capacity kept at 249 m Ah / g after 100 cycles at 0. 2 C.
作者 蒿豪 李佳 姚一一 王兵
机构地区 上海电气集团股份有限公司中央研究院
出处 《电池》 CAS CSCD 北大核心 2015年第1期48-50,共3页 Battery Bimonthly
基金 上海市科委"创新行动计划"社会发展领域科技计划-节能减排专项(12dz1200400)
关键词 锂离子电池 正极材料 磷酸铋(BiPO4) 包覆 Li-ion battery cathode material bismuth phosphate（BiPO4） coating
分类号 TQ131.11 [化学工程—无机化工] TM912 [电气工程—电力电子与电力传动]
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参考文献5

  • 1李会峰,庞静,杨允杰,卢世刚.Li[Li_(0.2)Mn_(0.54)Ni_(0.13)Co_(0.13)]O_2的界面电化学行为[J].电池,2013,43(4):186-188. 被引量：4
  • 2王海涛,段小刚,仇卫华.Al_2O_3包覆LiNi_(0.8)Co_(0.1)Mn_(0.1)O_2的结构和性能[J].电池,2014,44(2):84-87. 被引量：7
  • 3Wang Z Y,Zhao N Q,He C N,et al. Effect of amorphous FeP04coating on structure and electrochemical performance of Lij 2Ni0 13Co0 i3 Mn0.54 02 as cathode material for Li-ion batteries [ J ].J Power Sources,2013,236:25 - 32.
  • 4Zheng J M, Wu X B, Yang Y. Improved electrochemical perfor-mance of Li [ Lig 2 Mn0 54 Ni0 13 Co0 13 ] 02 cathode material by fluo-rine incorporation[ J]. Electrochim Acta,2013 ,105 :200 -208.
  • 5Wu F, Wang Z,Su Y F. Li[ Li0.2 Mn0.54 Ni0.13 Co0.13 ] 02-Mo03composite cathodes with low irreversible capacity loss for lithiumion batteries[ J]. J Power Sources,2014,247 :20 -25.

二级参考文献20

  • 1He W, Qian J F, Cao Y L,et aL Improved electrochemical perfor- mances of nanocrystalline Li [ Li0. 2 Mno. 54 Nio: 13 Coo. 13 ] 02 cathode material for Li-ion batteries [ J ]. RSC Advances, 2012,2 : 3 423 - 3 429.
  • 2Zhao T L,Chen S,Li L,et al. Synthesis,characterization,and elec- trochemistry of cathode material Li [ Lio.2 Coo. 13 Ni0.13 Mn0.s4 ] 02 using organic chelating agents for lithium-ion batteries[ J]. J Power Sources,2013,228:206 -213.
  • 3Hong J, Lim H D, Lee M,et al. Critical role of oxygen evolved from layered Li-excess metal oxides in lithium rechargeable batteries [ J]. Chemistry Materials,2012,24(14) :2 692 -2 697.
  • 4Armstrong A R,Robertson A D,Bruce P G J. Overcharging manga- nese oxides: extracting lithium beyond Mn4 ： [ J ]. J Power Sources, 2005,146( 1 ) i275 -280.
  • 5IJUShi-gang(卢世刚),ZHUANGWei-dong(庄卫东),SUNXue-yi(孙学义),etaL一种富锂材料的制备方法[P].cN:201110337732.6.2011-10-18.
  • 6Yu H J,Kim H,Wang Y,et al. High-energy 'composite' layered manganese-rich cathode materials via controlling Li2MnO3 phase activation for lithium-ion batteries [ J']. Phys Chem Chem Phys, 2012,14(18) :6 584 -6 595.
  • 7Johnson C S, Kim J S, Lefief C, et al. The significance of the Li2 MnO3 component in ' composite' xLi2 MnO3 ： ( 1-x ) LiMn0. 5 Ni0.502 electrodes[J]. Electrochem Commun,2004,6(10) :1 085 -1 091.
  • 8Mohanty D, Kalnaus S, Meisner R A, et al. Structural transforma- tion of a lithium-rich LiE 2 Coo. 1 Mno. 55 Ni0. t5 02 cathode during high voltage cycling resolved by in situ X-ray diffraction [ J]. J Power Sources,2013,229 : 239 - 248.
  • 9Martha S K, Nanda J, Veith G M, et al. Surface studies of high vol- tage lithium rich composition: Lil. 2 Mno. 525 Ni0.175 Coo. 1 02 [ J ]" J Power Sources ,2012,216 : 179 - 186.
  • 10Martha S K, Nanda J, Veith G M, et al. Electrochemical and rate performance study of high-voltage lithium-rich composition: LiE2 Mn0. 525 Nio. 175 Coo. t 02 [ J ] .J Power Sources, 2012,199 : 220 - 226.

共引文献9

同被引文献37

  • 1王丽,易华.丁二酮肟重量法对泵轴中镍含量的测定[J].化学工程师,2005,19(9):44-44. 被引量：9
  • 2XIANG Y H, YIN Z, ZHANG Y H. Effects of synthesis conditions on the structural and electrochemical properties of the Li-rich ma- terial Li [ Li0. 2 Ni0. 17 Co0.16 Mn0. 47 ] O2 via the solid-state method [J]. Electrochim Acta, 2013,91:214 -218.
  • 3SON J T, JEON H J, LIM J B. Synthesis and electrochemical characterization of Li2MnO3-LiNixCoyMnx O2 cathode for lithium battery using co-precipitation method [ J ]. Adv Powder Technol, 2013, 24( 1 ) :270 -274.
  • 4WANG Z, WU F, SU Y F. Synthesis and electrochemical perfor- mance of Li [ Li0. 2 Mn0. 54 Ni0. 13 Co0. 13 ] O2 cathode materials for li- thium-ion batteries[ J]. Acta Phys Chim Sin, 2012, 28 ( 1 ) :823 - 828.
  • 5JIA Yong-zhong(贾永忠),YAO Ying(姚颖),JING Yan(景燕),et al.燃烧法制备锂离子电池正极材料的方法[P].CN:200610105308.8.2006-12-14.
  • 6ZHANG Yang-zu(张扬祖).原子吸收光谱分析技术应用基础[M].shanghai(上海):Press of East China University of Science and Technology(华东理工大学出版社),2007.
  • 7国务院 .《节能与新能源汽车产业发展规划( 2012-2020 年) 》( Z) . 2012-06-28.
  • 8ITO A,SATO Y,SANADA T,et al. In situ X-ray absorption spec-troscopic study of Li-rich layered cathode material Li[Ni0. 17Li0. 2Co0. 07Mn0. 56]O2[J]. J Power Sources,2011,196( 16) : 6 828 -6 834.
  • 9AMINE K,CHEN Z H,KANG S H. Impacts of fluorine on theelectrochemical properties of Li[Ni0. 5Mn0. 5]O2and Li[Li0. 2Ni0. 15Co0. 1Mn0. 55]O2[J]. J Fluorine Chem,2007,128( 4) : 263-268.
  • 10TANG Z H,WANG Z X,LI X H,et al. Preparation and elec-trochemical properties of Co-doped and none-doped Li[LixMn0. 65( 1-x)Ni0. 35( 1-x)]O2cathode materials for lithium battery batteries[J].J Power Sources,2012,24( 15) : 187-192.

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电池
2015年 第1期

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