期刊文献+

Fe-SAPO-5分子筛纯化二氧化碳的研究 被引量:1

Investigation of Fe-SAPO-5 Molecular Sieve for Purification of Carbon Dioxide
下载PDF
导出
摘要 采用水热合成法制备了SAPO-5分子筛,并通过浸渍法制备了一系列的Fe-SAPO-5吸附剂,并通过XRD和IR手段对其进行表征。以Fe-SAPO-5作为吸附剂进行二氧化碳气体的提纯精制研究,并研究了不同负载量、温度及空速对其性能的影响。实验结果表明,在反应温度为25℃,压力1.0 MPa,空速为80 m L/min的条件下,9%(wt)Fe Ox/SAPO-5吸附效果最佳,产品纯度可达99.99%。 SAPO-5 molecular was synthesized by hydrothermal method, andthenthe Fe-SAPO-5 sorbent was prepared by impregnation method. The sample was characterized by means of XRD and IR techniques. The Fe-SAPO-5 sorbent was usedtopurifycarbondioxide.Effectofdifferent load, temperature and space velocityon properties of prepared sorbent was investigated.The results show thatwhenthe experimentaltemperature is25℃,the pressure is1 MPa andspace velocityis80 mL/minand FeOXcontentis 9 %(wt), thepurityof CO2can reach to 99.99%.
作者 佟天宇
出处 《当代化工》 CAS 2015年第3期448-450,453,共4页 Contemporary Chemical Industry
基金 FSKJHT项目号:201256
关键词 高纯二氧化碳 Fe-SAPO-5分子筛 水热合成法 提纯精制 吸附 High-purity CO2 SAPO-5 molecular sieve Hydrothermal synthesis method Purification Adsorption
  • 相关文献

参考文献5

  • 1周家贤.全绿色化工的进展及前景[J].化工设计,2010,20(1):3-7. 被引量:8
  • 2黄汉生.温室效应气体二氧化碳的回收与利用[J].现代化工,2001,21(9):53-57. 被引量:26
  • 3Wilson S T, Lok B M, Flanigen E M. Crystalline metallophosphate compositions: USA,4310440[P]. 1982-01-12.
  • 4Yoo K S, Kim J H, Park M J, et al. Influence of solid acid catalyst on DME production directly from synthesis gas over the admixed catalyst of Cu/ZnO/Al2O3 and various SAPO catalysts[J]. Applied Catalysis A: General, 2007, 330: 57-62.
  • 5Chen H J, Matsuoka M, Zhang J L, et al. The effect of the Si/Al ratio on the photoluminescence properties of Cu(I) SAPO-5 catalysts[J]. Chem Lett, 2004, 33(10): 1254-1255.

二级参考文献29

共引文献32

同被引文献20

  • 1许元栋,马波,凌凤香,张喜文,兰权,韩晓昱.中微孔结构沸石分子筛的合成研究进展[J].当代化工,2005,34(2):85-88. 被引量:3
  • 2卢涛,佟德斌.饱和含水土壤埋地原油管道冬季停输温降[J].北京化工大学学报(自然科学版),2006,33(4):37-40. 被引量:39
  • 3Christian Fernandez,Irina Stan,Jean-Pierre Gilson. Hierarchical ZSM-5 Zeolites in Shape-Selective Xylene Isomerization:Role of Mesoporosity and Acid Site Speciation[J]. Chem. Eur. J. 2010, 16, 6224-6233.
  • 4BENAZZI E, GUTH J L, ROULEAU L. IM-5 zeolite, a processing for its preparation and catalytic applications thereof: US, 6136290[P]. 2000-10-24.
  • 5CORMA A, CHICA A, GUIL J M. Determination of the pore topology of zeolite IM-5 by means of catalytic test reactions and hydrocarbon adsorption measurements[J]. Journal of Catalysis, 2000, 189:382 - 394.
  • 6WANG L, YANG W Y, LING F X. A facile method for the fabrication of IM-5 hollow zeolite sphere in emulsion system[J]. Microporous and Mesoporous Materials, 2012, 163: 243-248.
  • 7LEE S H, LEE D K, SHIN C H. Synthesis, characterization and catalytic properties of zeolites IM-5 and NU-88[J]. Journal of Catalysis, 2003, 215(1): 151-170.
  • 8PALOMARES A E, MARQUEZ F,VALENCIA S.On the researching of a new zeolite structure for the selective catalytic reduction of NO:The possibilities of Cu-exchanged IM-5[J]. Journal of Molecular Catalysis A: Chemical, 2000, 162(1-2): 175-189.
  • 9PALOMARES A E, PRATO J G, CORMA A. Co-exchanged IM-5, a stable zeolite for the selective catalytic reduction of NO in the presence of water and SO2[J]. Industrial & Engineering Chemistry Research, 2003, 42(8): 1538-1542.
  • 10CORMA A,MARTNEZ-TRIGUERO J, VALENCIA S. IM-5: A highly thermal and hydrothermal shape-selective cracking zeolite[J]. Journal of Catalysis, 2002, 206(1): 125-133.

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部